To meet the growing electricity demand, China’s power generation sector has become an increasingly large source of air pollutants. Specific control policymaking needs an inventory reflecting the overall, heterogeneous, time-varying features of power plant emissions. Due to the lack of comprehensive real measurements, existing inventories rely on average emission factors that suffer from many assumptions and high uncertainty. This study is the first to develop an inventory of particulate matter (PM), SO₂ and NO_X emissions from power plants using systematic actual measurements monitored by China’s continuous emission monitoring systems (CEMS) network over 96–98% of the total thermal power capacity. With nationwide, source-level, real-time CEMS-monitored data, this study directly estimates emission factors and absolute emissions, avoiding the use of indirect average emission factors, thereby reducing the level of uncertainty. This dataset provides plant-level information on absolute emissions, fuel uses, generating capacities, geographic locations, etc. The dataset facilitates power emission characterization and clean air policy-making, and the CEMS-based estimation method can be employed by other countries seeking to regulate their power emissions.

As the world’s largest industrial producer, China has generated large amount of industrial atmospheric pollution, particularly for particulate matter (PM), SO₂ and NO_x emissions. A nationwide, time-varying, and up-to-date air pollutant emission inventory by industrial sources has great significance to understanding industrial emission characteristics. Here, we present a nationwide database of industrial emissions named Chinese Industrial Emissions Database (CIED), using the real smokestack concentrations from China’s continuous emission monitoring systems (CEMS) network during 2015–2018 to enhance the estimation accuracy. This hourly, source-level CEMS data enables us to directly estimate industrial emission factors and absolute emissions, avoiding the use of many assumptions and indirect parameters that are common in existing research. The uncertainty analysis of CIED database shows that the uncertainty ranges are quite small, within ±7.2% for emission factors and ±4.0% for emissions, indicating the reliability of our estimates. This dataset provides specific information on smokestack concentrations, emissions factors, activity data and absolute emissions for China’s industrial emission sources, which can offer insights into associated scientific studies and future policymaking.