Biomass-based solutions have been discussed as having the potential to replace fossil-based solutions in the iron and steel industry. To produce the biocarbon required in these processes, thermochemical treatment, pyrolysis, typically takes place. There are various ways to produce biocarbon, alongside other products, which are called pyrolysis oil and pyrolysis gas. These conversion methods can be divided into conventional and non-conventional methods. In this paper, those techniques and technologies to produce biocarbon are summarized and reviewed. Additionally, the effect of different process parameters and their effect on biocarbon yield and properties are summarized. The process parameters considered were final pyrolysis temperature, heating rate, reaction atmosphere, pressure, catalyst, use of binders, and particle size. Finally, the effect of different reactor configurations is discussed. Understanding the combination of these methods, technology parameters, and reactor configurations will help to produce biocarbon with the desired quality and highest yield possible.

A transient computational fluid dynamics (CFD) modelling approach was used to study the complex multi-phase flow in an argon-stirred industrial scale ladle with a nominal capacity of 150 tons. During the stirring process, when gas was injected through the porous plug from the bottom into the steel bath, it breaks up into bubbles and infringes the slag layer creating an open-eye. The volume of fluid model was used to investigate the open-eye formation process in the simulations. In the numerical simulations, the open-eye area changed from 0.7 to 2.24 m² with the increment of argon flow rate from 200 to 500 NL/min for slag layer thickness of 40 cm. Furthermore, the influence of slag layer height on the open-eye area was investigated. An argon flow rate of 200 NL/min was able to break the slag layer for slag layer height of 40 cm, and the open-eye formation was not possible for the same flow rate when the slag layer height was elevated from 40 to 55 cm. The numerical simulation results were validated against industrial measurements carried out at Outokumpu Stainless located in Tornio, Finland. The numerical simulation results of dynamics and time-averages of the slag area showed a good agreement when compared to the industrial measurements. To conclude, it is necessary to define gas flow rate based on the slag layer height to have an open-eye suitable for alloying.

In secondary metallurgy, argon gas stirring and alloying of elements are very important in determining the quality of steel. Argon gas is injected through the nozzle located at the bottom of the ladle into the molten steel bath; this gas breaks up into gas bubbles, rising upwards and breaking the slag layer at high gas flow rates, creating an open-eye. Alloy elements are added to the molten steel through the open-eye to attain the desired steel composition. In this work, experiments were conducted to investigate the effect of argon gas flow rate on the open-eye size and mixing time. An Eulerian volume of fluid (VOF) approach was employed to simulate the argon/steel/slag interface in the ladle, while a species transport model was used to calculate the mixing time of the nickel alloy. The simulation results showed that the time-averaged value of the open-eye area changed from 0.66 to 2.36 m² when the flow rate of argon was varied from 100 to 500 NL/min. The mixing time (95% criterion) of tracer addition into the metal bath decreased from 139 s to 96 s, when the argon flow rate was increased from 100 to 500 NL/min. The model validation was verified by comparing with measured experimental results.

There has been a rising interest in the iron and steel industry in replacing fossil-based carbon carriers in their processes because they are the main origin of the anthropogenic carbon emissions within the industry. The use of bio-based carbon carriers could be one solution to partly tackle this challenge. Conventionally, biocarbon is produced by pyrolysis with fixed heating rate, pyrolysis temperature, and retention time. Although the mechanisms behind the formation of biocarbon and the decomposition temperatures of the main compounds of biomass-based materials are known, this knowledge is rarely being utilized in the design of commercial pyrolysis reactors, even though the pyrolysis mechanism-based approach increases the biocarbon yield. In this study, the mechanistic pathway of carbonization of lignocellulosic biomass is taken into account to produce biocarbon with higher yield and quality than conventional pyrolysis with the same process time. Results show that when the process time is the same in both methods, segmented pyrolysis increases biocarbon yield up to 5.4% within a pyrolysis temperature range from 300 °C to 900 °C. Also, fixed carbon yield increased 1.5% in this temperature area. When using segmented pyrolysis, the most suitable pyrolysis temperature is 700 °C based on the characteristics of the produced biocarbon.