One-dimensional mesoporous TiO2–Bi2WO6 hollow superstructures are prepared using a hydrothermal method and their photocatalysis and recycle properties are investigated. Experimental results indicate that anatase TiO2 nanoparticles are coupled with hierarchical Bi2WO6 hollow tubes on their surfaces. The TiO2–Bi2WO6 structure has a mesoporous wall and the pores in the wall are on average 21 nm. The hierarchical TiO2–Bi2WO6 heterostructures exhibit the highest photocatalytic activity in comparison with P25, pure Bi2WO6 hollow tube and mechanical mixture of Bi2WO6 tube and TiO2 nanoparticle in the degradation of rhodamine B (RhB) under simulated sunlight irradiation. The as-prepared TiO2–Bi2WO6 heterostructures can be easily recycled through sedimentation and they retains their high photocatalytic activity during the cycling use in the simulated sunlight-driving photodegradation process of RhB. The prepared mesoporous TiO2–Bi2WO6 with hollow superstructure is therefore a promising candidate material for water decontamination use.
11 September 2023 in Journal of Colloid and Interface Science
Gene therapy has attracted much attention because of its unique mechanism of action, non-toxicity, and good tolerance, which can kill cancer cells without damaging healthy tissues. siRNA-based gene therapy can downregulate, enhance, or correct gene expression by introducing some nucleic acid into patient tissues. Routine treatment of hemophilia requires frequent intravenous injections of missing clotting protein. The high cost of combined therapy causes most patients to lack the best treatment resources. siRNA therapy has the potential of lasting treatment and even curing diseases. Compared with traditional surgery and chemotherapy, siRNA has fewer side effects and less damage to normal cells. The available therapies for degenerative diseases can only alleviate the symptoms of patients, while siRNA therapy drugs can upregulate gene expression, modify epigenetic changes, and stop the disease. In addition, siRNA also plays an important role in cardiovascular diseases, gastrointestinal diseases, and hepatitis B. However, free siRNA is easily degraded by nuclease and has a short half-life in the blood. Research has found that siRNA can be delivered to specific cells through appropriate vector selection and design to improve the therapeutic effect. The application of viral vectors is limited because of their high immunogenicity and low capacity, while non-viral vectors are widely used because of their low immunogenicity, low production cost, and high safety. This paper reviews the common non-viral vectors in recent years and introduces their advantages and disadvantages, as well as the latest application examples.
Flexible titanium carbide (Ti3C2) antenna offers a breakthrough in the penetration of information communications for the spread of Internet of Things (IoT) applications. Current configurations are constrained to multi-layer complicated designs due to the limited conformal integration of the dielectric substrate and additive-free Ti3C2 inks. Here, we report the flexible ultrawideband Ti3C2 monopole antenna by combining strategies of interfacial modification and advanced extrusion printing technology. The polydopamine, as molecular glue nano-binder, contributes the tight adhesion interactions between Ti3C2 film and commercial circuit boards for high spatial uniformity and mechanical flexibility. The bandwidth and center frequency of Ti3C2 antenna can be well maintained and the gain differences fluctuate within ±0.2 dBi at the low frequency range after the bent antenna returns to the flat state, which conquers the traditional inelastic Cu antenna. It also achieves the demo instance for the fluent and stable real-time wireless transmission in bending states.
21 December 2023 in Angewandte Chemie International Edition