Photoresponsive fluorochromic materials are regarded as an effective means for information storage. Their reversible changes of color and fluorescence facilitate the storage process and increase the possible storage capacity. Here, we propose an optically reconfigurable Förster resonance energy transfer (FRET) process to realize tunable emissions based on photochromic spiropyrans and common fluorophores. The kinetics of the photoisomerization of the spiropyran and the FRET process of the composite were systematically investigated. Through tuning the ratios of the acceptor spiropyran and donor fluorophore and external light stimuli, a programmable FRET process was developed to obtain tunable outputs. More importantly, flexible microarrays were fabricated from such fluorochromic mixtures by inkjet printing (230 ppi) and the dynamic FRET process could also be applied to generate tunable fluorescence in ready-made microstructures. The flexible patterns created using the microarrays could be used as novel optically readable media for information storage by altering the composition and optical performance of every feature within the microarray. A key aspect of information storage such is anti-counterfeiting, and these colorful displays can be fabricated and integrated in a simple and straightforward system. The reliable fabrication and programmable optical performances of these large-scale flexible polymer microarrays represent a substantial step toward high-density and high-security information storage platforms.

This paper provides a review of advances in conjugated polymer lasers. High photoluminescence efficiencies and large stimulated emission cross-sections coupled with wavelength tunability and low-cost manufacturing processes make conjugated polymers ideal laser gain materials. In recent years, conjugated polymer lasers have become an attractive research direction in the field of organic lasers and numerous breakthroughs based on conjugated polymer lasers have been made in the last decade. This paper summarizes the recent progress of the subject of laser processes employing conjugated polymers, with a focus on the photoluminescence principle and excitation radiation mechanism of conjugated polymers. Furthermore, the effect of conjugated polymer structures on the laser threshold is discussed. The most common polymer laser materials are also introduced in detail. Apart from photo-pumped conjugated polymer lasers, a direction for the future development of electro-pumped conjugated polymer lasers is proposed.

Subwavelength optical micro/nanofibers have several advantages, such as compact optical wave field and large specific surface area, which make them widely used as basic building blocks in the field of micro-nano optical waveguide and photonic devices. Among them, polymer micro/nanofibers are among the first choices for constructing micro-nano photonic components and miniaturized integrated optical paths, as they have good mechanical properties and tunable photonic properties. At the same time, the structures of polymer chains, aggregated structures, and artificial microstructures all have unique effects on photons. These waveguided micro/nanofibers can be made up of not only luminescent conjugated polymers, but also nonluminous matrix polymers doped with luminescent dyes (organic and inorganic luminescent particles, etc.) due to the outstanding compatibility of polymers. This paper summarizes the recent progress of the light-propagated mechanism, novel design, controllable fabrication, optical modulation, high performance, and wide applications of the polymer micro/nanofiber fluorescence waveguide. The focus is on the methods for simplifying the preparation process and modulating the waveguided photon parameters. In addition, developing new polymer materials for optical transmission and improving transmission efficiency is discussed in detail. It is proposed that the multifunctional heterojunctions based on the arrangement and combination of polymer-waveguided micro/nanofibers would be an important trend toward the construction of more novel and complex photonic devices. It is of great significance to study and optimize the optical waveguide and photonic components of polymer micro/nanofibers for the development of intelligent optical chips and miniaturized integrated optical circuits.

A new stimuli-responsive compound whose optical properties were significantly affected by acid was synthesized, combined with spiropyran and used for high-level information encryption taking advantage of their orthogonal responsiveness to external stimuli.