A parallel array of isolated metal nanowires is expected to be hydrophilic. We show, however, that a clustering of such nanowires brought about by vacuum drying produces a 'dual-scale roughness' and confers a strongly hydrophobic property to the surface. The mean size of the nanowire clusters as well as the contact angle are both found to be related to the wire length, and the critical wire length above which the surface becomes hydrophobic is ≈10 µm. Surface roughness is generally known to enhance water-repellent properties, but this is the first report of roughness-induced hydrophobicity on a bare (uncoated) metallic surface.
In this study, cement-treated waste sand as a by-product material produced from Al-Ahsa quarries (Saudi Arabia) was experimentally tested and investigated as a base course material for the foundation of structures and roads. The study aimed to use the waste sand as a construction material by improving its strength, bearing capacity, and stiffness. The waste sand was mixed with different percentages of Portland cement content (0, 2, 4, 6, and 8%) at the maximum dry density and optimum water content of the standard Proctor compaction conditions of a non-treated sample. Unconfined compressive strength and California Bearing Ratio (CBR) tests for different curing times were conducted. X-ray diffraction (XRD), laser-scanning microscopy (LSM), and X-ray spectroscopy (XPS) were used to explore the microstructure and composition of the treated sand. The results showed that the compressive strength, initial tangent modulus, and CBR of the treated sand increase with the increase in cement content and curing time. Furthermore, good correlations were established among the strength, initial tangent modulus, and CBR. Based on the obtained results, cement-stabilized waste sand is a potential material for use in construction. This is expected to save the environment and reduce the cost of road construction.
Waste tissues such as mammalian bone are a valuable source from which to extract hydroxyapatite. Camel bone-based hydroxyapatite (CBHA) was extracted from the femur of camel bones using a defatting and deproteinization procedure. The extracted CBHA was mechanically, chemically, physically, morphologically and structurally characterized. Fourier-Transform Infra-Red (FTIR) spectra, Micro-Raman, and X-ray diffraction analysis confirmed successful extraction of hydroxyapatite. The mechanical properties of the CBHA scaffold were measured using a Universal Instron compression tester. Scanning electron microscopy showed the presence of a characteristic interconnected porous architecture with pore diameter ranging from 50–600 µm and micro-computer tomography (Micro-CT) analysis identified a mean porosity of 73.93. Thermogravimetric analysis showed that the CBHA was stable up to 1000 °C and lost only 1.435% of its weight. Inductively coupled plasma–mass spectrometry (ICP-MS) and Energy-dispersive-X-ray (EDX) analysis demonstrated the presence of significant amounts of calcium and phosphorus and trace ions of sodium, magnesium, zinc, lead and strontium. Following 21 days of incubation in simulated body fluid (SBF), the pH fluctuated between 10–10.45 and a gradual increase in weight loss was observed. In conclusion, the extracted CBHA is a promising material for future use in bone tissue regeneration applications.