Rafael Block Samulewski

Dr. Rafael Block Samulewski

orcid

Research Focus & Metrics

Academic Career Length

17Years (2010-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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19 April 2019 in Polymers
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Journal Article
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Manuel LISManuel LIS
Manuel LIS
BCBianca Bastos Caruzi
Bianca Bastos Caruzi
GGGuilherme Gil
Guilherme Gil
RSRafael Block Samulewski
Rafael Block Samulewski
ABAlesandro Bail
Alesandro Bail
Fabricio BezerraFabricio Bezerra
Fabricio Bezerra
The use of Metal-Organic Frameworks (MOF) such as HKUST-1 in textiles is an alternative with regard to the development of technologies that are increasingly seeking for functionalities, mainly in the fields of health and hygiene, named biofunctional fabrics. However, the application of the MOF under the surface of the wool fiber can lead to a low durability finish due to its low fixation. Thus, this project aims to perform the direct synthesis of HKUST in the wool fiber, so that a product with good washing durability can be obtained. The purpose of this study was to incorporate metal-organic frameworks, composed of copper and trimesic acid, into woolen fabrics, to improve the antibacterial properties. The synthesis was performed directly in the wool fabric, at time intervals of 24 and 48 h. The resulting fabrics were characterized by Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), X-Ray Diffractometry (XRD), Fourier Transform Spectroscopy Infrared-Attenuated Total Reflectance (FTIR-ATR), and colorimetric analysis (CIElab), and the Antimicrobial Activity Test (American Association of Textile Chemist and Colourists - AATCC Test Method 61-2007-2A) was performed. The results suggested that the application produced textiles with antibacterial properties, showing activity against Escherichia coli.

23 June 2021 in Materials
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Journal Article
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RGRafaela Stefanie Gabardo
Rafaela Stefanie Gabardo
DCDayane Samara de Carvalho Cotre
Dayane Samara de Carvalho Cotre
Manuel LISManuel LIS
Manuel LIS
MMMurilo Moisés
Murilo Moisés
BFBruna Thaisa Martins Ferreira
Bruna Thaisa Martins Ferreira
Fabricio BezerraFabricio Bezerra
Fabricio Bezerra
Polyester fibers (PES) are the most consumed textile fibers due to their low water absorption; non-ionic character and high crystallinity. However, due to their chemical structure, the chemical interactions between polyester, finishing products, and dyes are quite challenging. We report on the use of ozone to modify the surface of polyester fibers with the goal of improving the interaction of the modified surface with finishing compounds and dyes. We used C.I. Disperse Yellow 211 to dye ozone-treated polyester fabrics and evaluated the effects of ozone treatment using FTIR-ATR, Raman spectroscopy, SEM imaging, rubbing tests, and capillarity measurements. We evaluated the dyeing performance via color analysis, and determined the dyeing kinetics. Experimental results indicate that the modification of polyester fabrics with ozone is a feasible pre-treatment that improves dyeing efficiency allowing better solidity of color and a decrease in the amount of dye required.

5 June 2019 in The Journal of the Textile Institute
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Journal Article
Closed access
JFJuliana Oliveira Fiedler
Juliana Oliveira Fiedler
ÓCÓscar García Carmona
Óscar García Carmona
CCCarlos García Carmona
Carlos García Carmona
MLManuel José Lis
Manuel José Lis
APAndre Mathias Souza Plath
Andre Mathias Souza Plath
Fabricio BezerraFabricio Bezerra
Fabricio Bezerra
The microencapsulation of essential oils and its application in textile articles allows the aggregation of different functionalities to the substrates, imparting them antimicrobial properties, cosmetic effects, UV protection, application of drugs, among others. Therefore, the coacervation technique allows good results using starch to prepare the microcapsules. The objective of this work was the microencapsulation of Aloe Vera with cornstarch using the simple coacervation technique in cotton nonwoven fabric using butane tetracarboxylic acid (BTCA) as a binding agent. Optical and Scanning electron microscopy were performed to understand the morphology of the microcapsules obtained; thermogravimetry, to the comprehension of the thermal degradation of the microcapsules; mass gain percentage; FTIR was used to prove the interaction between nonwoven and microcapsule and finally, the CIE WI white index. The micrography allowed the observation of granular morphology, predominantly angular. The thermogravimetric curves have shown two significative thermal events: dehydration of the oil and degradation of the starch. The samples presented darker coloration; however, their quality was not compromised by the finishing. For this reason, the characterizations allowed to infer that the simple coacervation using this method is a simple process, with good results for the encapsulation of essential oils.

1 August 2011 in Polyhedron
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Journal Article
Closed access
RSRafael Block Samulewski
Rafael Block Samulewski
JRJúlio César da Rocha
Júlio César da Rocha
RSRafael Stieler
Rafael Stieler
ELErnesto Schulz Lang
Ernesto Schulz Lang
DEDavid John Evans
David John Evans
FNFábio Souza Nunes
Fábio Souza Nunes

1 December 2010 in Journal of Molecular Structure
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Journal Article
Closed access
RSRafael Block Samulewski
Rafael Block Samulewski
JRJúlio César da Rocha
Júlio César da Rocha
OFOtávio Fuganti
Otávio Fuganti
RSRafael Stieler
Rafael Stieler
ELErnesto Schulz Lang
Ernesto Schulz Lang
FNFábio Souza Nunes
Fábio Souza Nunes

7 April 2020 in Discover Life
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Journal Article
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Dimas ZaiaDimas Zaia
Dimas Zaia
PCPaulo C. G. de Carvalho
Paulo C. G. de Carvalho
RSRafael Block Samulewski
Rafael Block Samulewski
RPRodrigo de Carvalho Pereira
Rodrigo de Carvalho Pereira
CZCássia Thaïs B.V. Zaia
Cássia Thaïs B.V. Zaia