The use of Metal-Organic Frameworks (MOF) such as HKUST-1 in textiles is an alternative with regard to the development of technologies that are increasingly seeking for functionalities, mainly in the fields of health and hygiene, named biofunctional fabrics. However, the application of the MOF under the surface of the wool fiber can lead to a low durability finish due to its low fixation. Thus, this project aims to perform the direct synthesis of HKUST in the wool fiber, so that a product with good washing durability can be obtained. The purpose of this study was to incorporate metal-organic frameworks, composed of copper and trimesic acid, into woolen fabrics, to improve the antibacterial properties. The synthesis was performed directly in the wool fabric, at time intervals of 24 and 48 h. The resulting fabrics were characterized by Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), X-Ray Diffractometry (XRD), Fourier Transform Spectroscopy Infrared-Attenuated Total Reflectance (FTIR-ATR), and colorimetric analysis (CIElab), and the Antimicrobial Activity Test (American Association of Textile Chemist and Colourists - AATCC Test Method 61-2007-2A) was performed. The results suggested that the application produced textiles with antibacterial properties, showing activity against Escherichia coli.
Polyester fibers (PES) are the most consumed textile fibers due to their low water absorption; non-ionic character and high crystallinity. However, due to their chemical structure, the chemical interactions between polyester, finishing products, and dyes are quite challenging. We report on the use of ozone to modify the surface of polyester fibers with the goal of improving the interaction of the modified surface with finishing compounds and dyes. We used C.I. Disperse Yellow 211 to dye ozone-treated polyester fabrics and evaluated the effects of ozone treatment using FTIR-ATR, Raman spectroscopy, SEM imaging, rubbing tests, and capillarity measurements. We evaluated the dyeing performance via color analysis, and determined the dyeing kinetics. Experimental results indicate that the modification of polyester fabrics with ozone is a feasible pre-treatment that improves dyeing efficiency allowing better solidity of color and a decrease in the amount of dye required.
5 June 2019 in The Journal of the Textile Institute
The microencapsulation of essential oils and its application in textile articles allows the aggregation of different functionalities to the substrates, imparting them antimicrobial properties, cosmetic effects, UV protection, application of drugs, among others. Therefore, the coacervation technique allows good results using starch to prepare the microcapsules. The objective of this work was the microencapsulation of Aloe Vera with cornstarch using the simple coacervation technique in cotton nonwoven fabric using butane tetracarboxylic acid (BTCA) as a binding agent. Optical and Scanning electron microscopy were performed to understand the morphology of the microcapsules obtained; thermogravimetry, to the comprehension of the thermal degradation of the microcapsules; mass gain percentage; FTIR was used to prove the interaction between nonwoven and microcapsule and finally, the CIE WI white index. The micrography allowed the observation of granular morphology, predominantly angular. The thermogravimetric curves have shown two significative thermal events: dehydration of the oil and degradation of the starch. The samples presented darker coloration; however, their quality was not compromised by the finishing. For this reason, the characterizations allowed to infer that the simple coacervation using this method is a simple process, with good results for the encapsulation of essential oils.