Deep eutectic solvents (DES) resemble ionic liquids but are formed from an ionic mixture instead of being a single ionic compound. Here we present some results that demonstrate that surfactant sodium dodecyl sulfate (SDS) remains surface-active and shows self-assembly phenomena in the most commonly studied DES, choline chloride/urea. X-ray reflectivity (XRR) and small angle neutron scattering (SANS) suggest that the behavior is significantly different from that in water. Our SANS data supports our determination of the critical micelle concentration using surface-tension measurements and suggests that the micelles formed in DES do not have the same shape and size as those seen in water. Reflectivity measurements have also demonstrated that the surfactants remain surface-active below this concentration.

Arsenic contamination of groundwaters in South and Southeast Asia is a major threat to public health. In order to better understand the geochemical controls on the mobility of arsenic in a heavily arsenic-affected aquifer in northern Kandal Province, Cambodia, key changes in inorganic aqueous geochemistry have been monitored at high vertical and lateral resolution along dominant groundwater flow paths along two distinct transects. The two transects are characterized by differing geochemical, hydrological and lithological conditions. Arsenic concentrations in groundwater are highly heterogenous, and are broadly positively associated with iron and negatively associated with sulfate and dissolved oxygen. The observed correlations are generally consistent with arsenic mobilization by reductive-dissolution of iron (hydr)oxides. Key redox zones, as identified using groupings of the PHREEQC model equilibrium electron activity of major redox couples (notably ammonium/nitrite; ammonium/nitrate; nitrite/nitrate; dissolved oxygen/water) have been identified and vary with depth, site and season. Mineral saturation is also characterized. Seasonal changes in groundwater chemistry were observed in areas which were (i) sandy and of high permeability; (ii) in close proximity to rivers; and/or (iii) in close proximity to ponds. Such changes are attributed to monsoonal-driven surface-groundwater interactions and are consistent with the separate provenance of recharge sources as identified using stable isotope mixing models.

Sub-Saharan Africa must urgently improve food security. Phosphorus availability is one of the major barriers to this due to low historical agricultural use. Shared socioeconomic pathways (SSPs) indicate that only a sustainable (SSP1) or a fossil fuelled future (SSP5) can improve food security (in terms of price, availability, and risk of hunger) whilst nationalistic (SSP3) and unequal (SSP4) pathways worsen food security. Furthermore, sustainable SSP1 requires limited cropland expansion and low phosphorus use whilst the nationalistic SSP3 is as environmentally damaging as the fossil fuelled pathway. The middle of the road future (SSP2) maintains today’s inadequate food security levels only by using approximately 440 million tonnes of phosphate rock. Whilst this is within the current global reserve estimates the market price alone for a commonly used fertiliser (DAP) would cost US$ 130 ± 25 billion for agriculture over the period 2020 to 2050 and the farmgate price could be two to five times higher due to additional costs (e.g. transport, taxation etc.). Thus, to improve food security, economic growth within a sustainability context (SSP1) and the avoidance of nationalist ideology (SSP3) should be prioritised.

The Fens is a region that contributes 11% of the agri-food economy from just 4% of the agricultural land covering England (UK). This region is vulnerable to soil salinisation from sea-level rise with estimated 100-year flood events projected to be observed up to every 2 years by 2100. Seawater intrusion and upwelling of saline groundwater can provide an additional pathway; however, the area’s groundwater has not been assessed and the risk is unknown. This study used data from the British Geological Survey’s stratigraphic core archive to produce the first stratigraphic map of the loosely consolidated Holocene deposits in the South Holland–Holbeach Marsh region. There is a sandy unconfined aquifer towards the coast, a semiconfined central region with a silty cap and a clay confining cap in the north region. Electrical resistivity tomography data indicate water level depths of 0.58 ± 0.37 m above mean sea level (msl) in February 2021 and 0.01 ± 0.72 m msl in August 2021. The saline–freshwater boundary was at 1.70 ± 0.82 m msl in February 2021, deepening to 2.00 ± 1.02 m msl in August 2021, but the only evidence of seasonal fluctuation was within 10 km of the coast. A potential, but unverified, freshwater lens up to 3.25 m thick may exist beneath the surface. These results suggest that freshwater–saline interface fluctuations may primarily be driven by surface hydrology and would be vulnerable to climate-change-induced future variations in factors that affect surface water.