During industrial glass production processes, the actual distribution of stress components in the glass during scribing remains, to date, poorly quantified, and thus continues to be challenging to model numerically. In this work, we experimentally quantified the effect of pressure and temperature on the viscosity of SCHOTT N‐ BK 7 ® glass, by performing in situ deformation experiments at temperatures between 550 and 595°C and confining pressures between 100 and 300 MPa. Experiments were performed at constant displacement rates to produce almost constant strain rates between 9.70 × 10 −6 and 4.98 × 10 −5 s −1 . The resulting net axial stresses range from 81 to 802 MPa, and the finite strains range from 1.4% to 8.9%. The mechanical results show that the SCHOTT N‐ BK 7 ® glass is viscoelastic near the glass transition temperature at 300 MPa of confining pressure. To elucidate the data, we incorporated both 1‐element and 2‐element generalized Maxwell viscoelastic models in an inversion approach, for which we provide MATLAB scrips. Results show that the 2‐element Maxwell model fits the experimental data well. The stress decreases with increasing temperature at 300 MPa and the temperature dependence yields a similar activation energy (601 ± 10 kJ mol −1 or ∆ H / R = 7.2 × 10 4 K) to a previously reported value at 1‐atm (615 kJ mol −1 or ∆ H / R = 7.4 × 10 4 K). The SCHOTT N‐ BK 7 ® glass shows a limited linear increase in viscosity with increasing pressure of ~0.1 log 10 (Pa·s)/100 MPa, which is in agreement with the most recent 2‐internal‐parameter relaxation model (based on experiments).
31 July 2020 in Journal of the American Ceramic Society
Basalt continuous fibers (BFs) have been widely applied in the construction industry including marine applications, however, the corrosion mechanism of BFs in a seawater environment is still not well understood. In this work, we explored the effect of the seawater environment on the weight loss, tensile strength, surface morphology, and microstructure structure of BFs via soaking the BFs in seawater solutions at different temperatures and durations. Results show that the weight loss ratio of BFs decreases at the first stage (around 18 h) of soaking at 80 °C, 85 °C, and 90 °C and then increases for longer soaking durations, while the tensile strength has the opposite change. This enhancement of tensile strength and chemical resistance (at the first stage of seawater soaking) is dominated by the ion-exchange induced ‘blunting’ mechanism, even though the results from a Fourier transform infrared (FT-IR) spectrometer and energy-dispersive spectroscopy (EDS) revealed the damaging of the Si–O–Si tetrahedral structure during the corrosion process. This work revealed the full corrosion process and corresponding mechanism of BFs in a seawater environment.