The use of ionic liquids as functional building blocks based on pyridinium, imidazolium and phosphonium cations to achieve materials combining a structuration at nanoscale with the dramatic mechanical properties of the resulting ionomers has been successfully demonstrated for the first time in a fluorinated matrix.

The PeakForce QNM AFM mode was used to investigate the nanoscale mechanical properties of poly(butylene-adipate-co-terephthalate)/poly(lactic acid) (PBAT/PLA) blends successfully compatibilized with phosphonium-based ionic liquids (ILs). This novel AFM mode allowed identification of the phase structuration and also emphasized the effect of the ionic liquids on the mechanical behavior at nanoscale of the polymer phases and interfaces. On one hand, phosphonium-chloride IL (il-Cl) was shown to play an efficient role as an interfacial agent, i.e., causing a finer dispersion of PLA nodules in the PBAT continuous matrix. On the other hand, phosphonium-phosphinate IL (il-TMP), leads to PLA dispersed as a fibril phase and located as an interphase layer between the two polymers. Adhesion force mappings confirmed that the ILs are mainly localized at the interfaces between the two polyesters. The PeakForce QNM AFM study allowed the proposal of complete models for the compatibilization mechanism, establishing relationships between the nanoscale structure and the macroscopic mechanical properties of these blends.

Carbon nanotube (CNT)-reinforced nanocomposites represent a unique opportunity in terms of designing advanced materials with mechanical reinforcement and improvements in the electrical and thermal conductivities. However, the toxic effects of these composites on human health have been studied, and very soon, some regulations on CNTs and on composites based on CNTs will be enacted. That is why the release of CNTs during the nanocomposite lifecycle must be controlled. As the releasing depends on the interfacial strength that is stronger between CNTs and polymers compared to CNTs in a CNT agglomerate, two dispersion states—one poorly dispersed versus another well dispersed—are generated and finely described. So, the main aim of this study is to check if the CNT dispersion state has an influence on the CNT releasing potential in the nanocomposite. To well tailor and characterize the CNT dispersion state in the polymer matrix, electronic microscopies (SEM and TEM) and also rheological analysis are carried out to identify whether CNTs are isolated, in bundles, or in agglomerates. When the dispersion state is known and controlled, its influence on the polymerization kinetic and on mechanical properties is discussed. It appears clearly that in the case of a good dispersion state, strong interfaces are generated, linking the isolated nanotubes with the polymer, whereas the CNT cohesion in an agglomerate seems much more weak, and it does not provide any improvement to the polymer matrix. Raman spectroscopy is relevant to analyze the interfacial properties and allows the relationship with the releasing ability of nanocomposites; i.e., CNTs poorly dispersed in the matrix are more readily released when compared to well-dispersed nanocomposites. The tribological tests confirm from released particles granulometry and observations that a CNT dispersion state sufficiently achieved in the nanocomposite avoids single CNT releasing under those solicitations.