Trace amounts of zirconium (Zr) have been adopted to modify the crystal structure and surface of the Ni-rich LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) cathode material. During cycling at 1.0C, the Zr-modified NCM811 shows an improved capacity retention of 92% after 100 cycles, higher than 75% for pristine NMC811. In addition, the Zr-modified NCM811 is capable of delivering a discharge capacity of 107 mA h g⁻¹ at a 10.0C rate, much higher than 28 mA h g⁻¹ delivered by pristine materials. These improved electrochemical performances are ascribed to the dual functions of Zr modification. On one hand, part of the Zr enters the crystal lattice, which is beneficial for reducing the Li/Ni cation mixing and enhancing the crystal stability of the cathode. On the other hand, the rest of the Zr forms a 1–2 nm thick coating layer on the surface of the NCM811 cathode, which effectively prevents direct contact between NCM and the electrolyte, thus suppressing the detrimental interfacial reactions. Therefore, the Zr-modified LiNi_0.8Co_0.1Mn_0.1O₂ exhibited significantly enhanced cycling stability and charge/discharge rate capability in comparison with its untreated counterpart.

In this work, a LiNi _1/3 Co _1/3 Mn _1/3 O ₂ /CNT/Graphene (NCM/CNT/GN) hybrid material with 3D conductive network and excellent rate capability has been successfully prepared by a facile wet chemical method.

An SrF₂ microsphere layer on a separator could be involved in SEI formation and result in a dendrite free SEI on a lithium anode.

Mn doping could form a stable LiMn_xFe_1−xPO₄ protective shell on the surface to suppress LiFePO₄ degradation during electrochemical cycling.