Cold recycled asphalt mixtures (CRAM) are a cost-effective and environmentally-friendly way to reuse reclaimed asphalt pavement (RAP). This paper evaluates the rheological properties and microstructure of mineral filler-asphalt mastic, mineral filler-residue mastic, and cement-residue mastic. Then, based on the premise of using 100% RAP with a gradation that was determined experimentally, the effects of emulsified asphalt and cement on the porosity, indirect tensile strength, tensile strength ratio, dynamic stability, and mechanical properties of CRAM were evaluated. It was found that the rheological properties and cohesive coefficient of the cement-residue mastic varied differently to those of the first two types of mastic and the results show that the addition of cement can greatly improve the interfacial bonding between binders and fillers in the mastic, thereby improving the water damage resistance and high-temperature stability of CRAM. The relationships between cement content and the dynamic modulus and phase angle of CRAM are different to that for emulsified asphalt obviously. In addition, under certain conditions, the properties of CRAM can meet the requirements of relevant technical specifications for its application to subsurface layer of pavement. Hence, the use of 100% RAP in CRAM may be feasible.

Atomic force microscopy (AFM) was used to explore the effects of graphene modifier on the microstructure of asphalt. The morphologies of the before- and after-aged base asphalt and modified asphalt were performed and compared with analysis. The formation mechanism of asphaltic “bee structures” and the influence mechanism of graphene on asphalt were discussed from the classical theory of material science (phase transformation theory and diffusion theory). The results show that graphene facilitates the nucleation of “bee structures”, resulting in an increasing number and decreasing volume of “bee structures” in modified asphalt. Additionally, the anti-aging performance of the modified asphalt improved significantly because of graphene incorporation.

Using an AMPT tester and based on laboratory tests, this paper performed a comparative study on the dynamic characteristics of different asphalt mixtures, analyzed the influence of different asphalt binders on the characteristic parameters of the dynamic modulus master curve and the phase angle master curve of asphalt mixture, and expounds the evaluation function of the phase angle master curve for mixture relaxation characteristics. The results show that the modulus master curve parameters of the asphalt mixture are closely related to voids in the mineral aggregate, mixture density, and asphalt content of the asphalt mixture. For the same kind of asphalt mixture, because the gradation of mineral aggregate is fixed and the volume parameters are almost the same, the ultimate modulus of the mixture at different temperatures is unique; when the temperature changes or the asphalt changes, the shape parameter β of the modulus master curve changes regularly, which brings different dynamic responses, and the lower β will show the characteristics of a higher modulus. Asphalt is the source of the viscoelasticity of the asphalt mixture. Although the influence of particle gradation of the mixture will bring about the change of modulus, the phase angle of the mixture depends on the viscoelastic properties of asphalt, and the initial phase angle in the main curve is positively correlated with asphalt penetration and negatively correlated with the softening point and viscosity, while the peak phase angle A is negatively correlated with penetration, and the softening point viscosity is positively correlated. The viscoelastic interval, represented by ω, is negatively correlated with penetration but positively correlated with the softening point and viscosity. The peak position, parameter ωc, of the phase angle master curve can evaluate the relaxation characteristics of the mixture, and the crack resistance of different mixtures can be compared without complex model calculation. In the comparison of the relaxation time of asphalt mixture, the relaxation time of foam cold-recycled mixture is the largest, which is significantly higher than that of other forms of cement mixture; the emulsified asphalt cold-recycled mixture is equivalent to AC20 and LSPM30 mixtures; the SBS-modified asphalt mixture has the best relaxation characteristics.

Crumb rubber modified bitumen (CRMB) has been widely used in pavement construction and provides an effective way to recycle waste tires and helps alleviate the “black pollution” problem. There are no current specifications regarding the appropriate mixing and compaction temperatures of the CRMB mixture. There is a direct relationship between the mixing and the compaction temperatures of the CRMB mixture and the viscosity of the CRMB mastic. In this study, we first prepared CRMB using crumb rubber powder and penetration grade 70 neat bitumen, then prepared the CRMB mastic using CRMB and fillers (limestone mineral powder and cement). Finally, we used the CRMB mastic and aggregate to make mixture specimens. The best air void of the specimens was subsequently used to demarcate the viscosity of the CRMB mastic, and the construction temperatures (including the mixing temperature and the compaction temperature) were calculated based on the viscosity of the CRMB mastic from the viscosity–temperature curves. Test results indicated that the best viscosity of the CRMB mastic was 2.7 ± 0.2 Pa·s and 3.9 ± 0.3 Pa·s that corresponded to the mixing and compaction temperatures, respectively.

In this study, the chemical structure of asphalt aging was analyzed and identified based on ¹H-NMR quantitative technology and chemometrics analysis. The characteristic full component information of 30 samples before and after aging from 5 different oil sources was measured by ¹H-NMR, and the results were converted into a data matrix. This study used PCA, HAC, OPLS-DA, and Fisher discriminant analysis to evaluate the change rules of the chemical composition of asphalt from different oil sources after aging. The results showed that the ¹H-NMR spectra of 30 asphalt samples were very similar, and hydrogen could be divided into 4 categories according to the chemical shift: H_A, H_α, H_β, and H_γ. The shapes of ¹H-NMR of asphalt samples from different oil sources showed slight differences, while the shapes of the ¹H-NMR spectra of asphalt samples with different aging degrees from the same oil source was basically the same. The results of PCA and HAC analysis showed that the samples of the same asphalt and asphalt with similar oil sources before and after aging were still in the same category, and the spatial distance was very close, while the spatial distance of asphalts from different oil sources was very different. The Fisher discriminant function established by PCA and HAC can be used to distinguish asphalt samples from different oil sources with an accuracy of up to 100%.