All dielectric materials including ceramics, semiconductors, biomaterials, and polymers have the property of flexoelectricity, which opens a fertile avenue to sensing, actuation, and energy harvesting by a broad range of materials. However, the flexoelectricity of solids is weak at the macroscale. Here, we achieve an ultrahigh flexoelectric effect via a composite foam based on PDMS and CCTO nanoparticles. The mass- and deformability-specific flexoelectricity of the foam exceeds 10,000 times that of the solid matrix under compression, yielding a density-specific equivalent piezoelectric coefficient 120 times that of PZT. The flexoelectricity output remains stable in 1,000,000 deformation cycles, and a portable sample can power LEDs and charge mobile phones and Bluetooth headsets. Our work provides a route to exploiting flexible and light-weight materials with highly sensitive omnidirectional electromechanical coupling that have applications in sensing, actuation, and scalable energy harvesting.
Silicon (Si) is a promising candidate as an anode material for lithium-ion batteries. However, its application is hindered by poor cycling stability and rate-capability due to structural degradation, resulting from large volume changes during cyclic charging and discharging. In this paper, we report that uniform-sized Si@void@C nanoparticles can be prepared by magnesiothermic reduction of SiO2@void@C. Si nanoparticles are in hollow carbon shells with a large void space between the carbon shell and particles. Thus, each Si particle can expand freely within the well-designed void space without destroying the outer carbon shell, and benefit the solid–electrolyte interphase film stabilization on the carbon shell. The new material shows a high capacity of 1598 mA h g−1 at a current density of 1 A g−1, a long cycle life of 1500 cycles with 85% capacity retention, and a high Coulombic efficiency of 99.6% as well, and might be a promising Si-based anode material for Li-ion battery applications.
Strain engineering, as a cutting-edge method for modulating the electronic structure of catalysts, plays a crucial role in regulating the interaction between the catalytic surface and the adsorbed molecules. The electrocatalytic performance is influenced by the electronic structure, which can be achieved by introducing the external forces or stresses to adjust interatomic spacing between surface atoms. The challenges in strain engineering research lie in accurately understanding the mechanical impact of strain on performance. This paper first introduces the basic strategy for generating the strain, summarizes the different strain generation forms and their advantages and disadvantages. The progress in researching the characterization means for the lattice strains and their applications in the field of electrocatalysis is also emphasized. Finally, the challenges of strain engineering are introduced, and an outlook on the future research directions is provided.
Electromagnetic protection materials are widely used in both military and civilian fields. However, the limited wave-absorbing band and low transparency of conventional electromagnetic protection materials are the impediment for extensive applications. Here, a transparent and electrically tunable wave-absorbing metamaterial for stealth technology and electromagnetic protection has been theoretically and experimentally realized. The trend of the absorption feature change in simulation is consistent with that of the experiment results. The main part of this material adopts a sandwich structure consisting of two layers of indium tin oxide (ITO) and one layer of glass in between. The upper ITO layer is periodically patterned and combined with varactor diodes, which function as a frequency-selective surface. The effective operating frequency range is in the S-band, which covers the common frequency band of WiFi and many other electronic devices. The wave absorbing performance of this material can be electronically tunable by changing the applied voltage. The main absorption peak can be up to 90% with a tunable amplitude range of 30% and a tunable frequency band range of 1 GHz, and the transmittance of the sample in the visible is 80.23%. The metamaterial has high performance on electromagnetic shielding, whose effectiveness is larger than 30 dB in the range of 2.6–3.95 GHz. This transparent and tunable metamaterial has great potential for the applications in electromagnetic protection and stealth.