Properties of Ga2O3 thin films deposited by electron‐beam evaporation from a high‐purity single‐crystal Gd3Ga5O12 source are reported. As‐deposited Ga2O3 films are amorphous, stoichiometric, and homogeneous. Excellent uniformity in thickness and refractive index was obtained over a 2 in. wafer. The films maintain their integrity during annealing up to 800 and 1200 °C on GaAs and Si substrates, respectively. Optical properties including refractive index (n=1.84–1.88 at 980 nm wavelength) and band gap (4.4 eV) are close or identical, respectively, to Ga2O3 bulk properties. Reflectivities as low as 10−5 for Ga2O3/GaAs structures and a small absorption coefficient (≊100 cm−1 at 980 nm) were measured. Dielectric properties include a static dielectric constant between 9.9 and 10.2, which is identical to bulk Ga2O3, and electric breakdown fields up to 3.6 MV/cm. The Ga2O3/GaAs interface demonstrated a significantly higher photoluminescence intensity and thus a lower surface recombination velocity as compared to Al2O3/GaAs structures.
was deposited on using atomic-layer deposition (ALD). Without any surface preparation or postthermal treatment, excellent electrical properties of heterostructures were obtained, in terms of low electrical leakage current density ( to ) and low interfacial density of states in the range of . The interfacial reaction and structural properties studied by high-resolution x-ray photoelectron spectroscopy (HRXPS) and high-resolution transmission electron microscopy (HRTEM). The depth profile of HRXPS, using synchrotron radiation beam and low-energy sputtering, exhibited no residual arsenic oxides at interface. The removal of the arsenic oxides from heterostructures during the ALD process ensures the Fermi-level unpinning, which was observed in the capacitance-voltage measurements. The HRTEM shows sharp transition from amorphous oxide to single crystalline semiconductor.
Measurements of the transport critical‐current density (Jc), magnetization Jc, and magnetoresistance in a number of bulk sintered samples of Y1Ba2Cu3Ox from several different laboratories indicate that the transport Jc is limited by weak‐link regions between high Jc regions. The weak‐link Jc has a Josephson character, decreasing by two orders of magnitude as the magnetic field is increased from 0.1 to 10 mT at 77 K. An examination of the grain‐boundary region in Y1Ba2Cu3Ox shows no observable impurities or second phases to the scale of the [001] lattice planes (∼12 Å). The effect of intrinsic conduction anisotropy is discussed. A current‐transfer model is proposed in which weak conduction along the c axis plays a role in limiting Jc at grain boundaries. Orienting the grains in the powder state during processing may result in enhanced transport Jc in bulk conductors.
A GaAs metal–oxide–semiconductor field-effect transistor (MOSFET) with thin Al2O3 gate dielectric in nanometer (nm) range grown by atomic layer deposition is demonstrated. The nm-thin oxide layer with significant gate leakage current suppression is one of the key factors in downsizing field-effect transistors. A 1 μm gate-length depletion-mode n-channel GaAs MOSFET with an Al2O3 gate oxide thickness of 8 nm, an equivalent SiO2 thickness of ∼3 nm, shows a broad maximum transconductance of 120 mS/mm and a drain current of more than 400 mA/mm. The device shows a good linearity, low gate leakage current, and negligible hysteresis in drain current in a wide range of bias voltage.
The optical functions of thin films have been determined by ellipsometry from 0.74–5 eV. Several electron-beam evaporated and rf magnetron sputtered films of different thicknesses were investigated using a multisample technique. Refractive index values comparable to those of bulk material are found. Cauchy dispersion model fits yield a high-frequency dielectric constant of 3.57. Above 4.7 eV a direct absorption edge is observed.