Pyrolysis of straw pellets and wood strips was performed in a fixed bed reactor. The chars, solid products of thermal degradation, were used as potential materials for activated carbon production. Chemical and physical activation processes were used to compare properties of the products. The chemical activation agent KOH was chosen and the physical activation was conducted with steam and carbon dioxide as oxidising gases. The effect of the activation process on the surface area, pore volume, structure and composition of the biochar was examined. The samples with the highest surface area (1349.6 and 1194.4 m²/g for straw and wood activated carbons, respectively) were obtained when the chemical activation with KOH solution was applied. The sample with the highest surface area was used as an adsorbent for model wastewater contamination removal.

This review deals with the technologies of limonene production from waste tyre pyrolysis. Thermal decomposition is attractive for tackling the waste tyre disposal problem, as it enables both: energy to be recovered and limonene to be obtained. This material management recycling of tyres is environmentally more beneficial than the burning of all valuable products, including limonene. Given this recoverability of materials from waste tyres, a comprehensive evaluation was carried out to show the main effect of process conditions (heating rate, temperature, pressure, carrier gas flow rate, and type of volatile residence and process times) for different pyrolytic methods and types of apparatus on the yield of limonene. All the results cited are given in the context of the pyrolysis method and the type of reactor, as well as the experimental conditions in order to avoid contradictions between different researchers. It is shown that secondary and side reactions are very sensitive to interaction with the above-mentioned variables. The yields of all pyrolytic products are also given, as background for limonene, the main product reported in this study.

Tires, conveyor belts, floor mats, and shoe soles form a main-stream of rubber waste. The amount of these used materials continuously increases due to development of the rubber market. Therefore, pro-ecological utilization (i.e., energy recycling instead of burning) and recovering valuable and recyclable materials becomes an urgent necessity. In this regard, this work was devoted to the chemical recycling of selected used rubber products, and it especially explores the possibility of limonene production. Different types of waste rubber were characterized and pyrolyzed at microgram and laboratory scales, and the results were compared. Additionally, the pyrolysis of tires, the most significant stream of rubber waste, was also conducted in a semi-technical scale reactor. The effectiveness of limonene formation in the liquid fractions obtained from different types of waste rubber was compared.

The thermal pyrolysis of agriculture biomass has been studied in a fixed-bed reactor, where the pyrolysis was conducted at a steady temperature of 800 °C. This work analyses the pyrolysis products of six agricultural wastes: pistachio husks, walnut husks, sunflower hulls, buckwheat husks, corncobs and coconut shells. The conducted research compared examples of large waste biomass streams from different parts of the world as a potential source of renewable energy. Additionally, the kinetics of the reaction with the activation energy were analyzed and calculated for all raw materials in pyrolysis process. Biochars are characterised by higher combustion heat in comparison to the raw material samples. The average value of the heat of combustion increased due to pyrolysis process from 10 MJ/kg, with minimal value of 2.7 MJ/kg (corncob) and maximum of 13.0 MJ/kg for coconut, which is also characterised by the maximal absolute combustion heating value (32.3 MJ/kg). The increase in calorific values varied from 15% to 172% (with 54% reference for wood chips), which indicates that charring is an effective method for increasing the energy concentration. The obtained biochar were compared with wood chips, which are widely used solid fuel of organic origin. The studied biomass-derived fuels are characterised by lower ash contribution than wood. An analogous observation was made for the obtained biochars, whose ash contribution was lower than for the chips in terms of both unit-mass and unit-combustion-heat. The main advantage of this method is the production of solid fuel from biomass, which increases the calorific value and bulk density of biochar in comparison to raw material.