Solvothermal reaction of a partially flexible ligand, H4L, and Cu(NO3)2·2.5H2O afforded two cross-linked Kagomé lattices of formula [Cu2(L)]n : an acs net sustained by novel trigonal prismatic supermolecular building blocks (SBBs) and the first example of a partially pillared Kagomé net.
In recent years, low-temperature SCR (Selective Catalytic Reduction) denitrification technology has been popularized in non-power industries and has played an important role in the control of industrial flue gas NOx emissions in China. Currently, the most commonly used catalysts in industry are V2O5-WO3(MoO3)/TiO2, MnO2-based catalysts, CeO2-based catalysts, MnO2-CeO2 catalysts and zeolite SCR catalysts. The flue gas emitted during industrial combustion usually contains SO2, moisture and alkali metals, which can affect the service life of SCR catalysts. This paper summarizes the mechanism of catalyst poisoning and aims to reduce the negative effect of NH4HSO4 on the activity of the SCR catalyst at low temperatures in industrial applications. It also presents the outstanding achievements of domestic companies in denitrification in the non-power industry in recent years. Much progress has been made in the research and application of low-temperature NH3-SCR, and with the renewed demand for deeper NOx treatments, new technologies with lower energy consumption and more functions need to be developed.
A flexible ligand with two 1,3-benzenedicarboxylate units has been used to construct a microporous metal–organic framework with pcu topology based on supramolecular building blocks (SBBs). The obtained Cu(II) MOF exhibits a noticeable CO2 adsorption hysteresis and a comparable methane adsorption capacity at room temperature.