An impact with a dash of volcanism: Around the time of the end-Cretaceous mass extinction that wiped out dinosaurs, there was both a bolide impact and a large amount of volcanism. Hull et al. ran several temperature simulations based on different volcanic outgassing scenarios and compared them with temperature records across the extinction event. The best model fits to the data required most outgassing to occur before the impact. When combined with other lines of evidence, these models support an impact-driven extinction. However, volcanic gases may have played a role in shaping the rise of different species after the extinction event. Science , this issue p. 266

Mercury (Hg) is increasingly being used as a sedimentary tracer of Large Igneous Province (LIP) volcanism, and supports hypotheses of a coincidence between the formation of several LIPs and episodes of mass extinction and major environmental perturbation. However, numerous important questions remain to be answered before Hg can be claimed as an unequivocal fingerprint of LIP volcanism, as well as an understanding of why some sedimentary records document clear Hg enrichment signals whilst others do not. Of particular importance is evaluating the impact of different volcanic styles on the global mercury cycle, as well as the role played by depositional processes in recording global Hg-cycle perturbations. Here, new mercury records of Cretaceous Oceanic Anoxic Event 2 (OAE 2: ∼94 Ma) and the latest Cretaceous (∼67–66.0 Ma) are presented. OAE 2 is associated with the emplacement of multiple, predominantly submarine, LIPs; the latest Cretaceous with subaerial volcanism of the Deccan Traps. Both of these connections are strongly supported by previously published trends towards unradiogenic osmium- (Os) isotope values in globally distributed sedimentary records. Hg data from both events show considerable variation between different locations, attributed to the effectiveness of different sediment types in registering the Hg signal, with lithologically homogeneous records documenting more clear Hg enrichments than sections with major changes in lithology such as limestones to claystones or organic-rich shales. Crucially, there is no geographically consistent signal of sedimentary Hg enrichment in stratigraphic records of either OAE 2 or the latest Cretaceous that matches Os-isotope evidence for LIP emplacement, indicating that volcanism did not cause a global Hg perturbation throughout the entire eruptive history of the LIPs formed at those times. It is suggested that the discrepancy between Os-isotope and Hg trends in records of OAE 2 is caused by the limited dispersal range of Hg emitted from submarine volcanoes compared to the global-scale distribution of Os. A similar lack of correlation between these two proxies in uppermost Cretaceous strata indicates that, although subaerial volcanism can perturb the global Hg cycle, not all subaerial eruptions will do so. These results highlight the variable impact of different volcanogenic processes on the efficiency of Hg dispersal across the globe. Factors that could influence the impact of LIP eruptions on the global mercury cycle include submarine versus subaerial volcanism, volcanic intensity or explosivity, and the potential contribution of thermogenic mercury from reactions between ascending magma and surrounding organic-rich sediments.

Significance: The Antarctic ice cap waxed and waned on astronomical time scales throughout the Oligo-Miocene time interval. We quantify geometries of Antarctic ice age cycles, as expressed in a new climate record from the South Atlantic Ocean, to track changing dynamics of the unipolar icehouse climate state. We document numerous ∼110-thousand-year-long oscillations between a near-fully glaciated and deglaciated Antarctica that transitioned from being symmetric in the Oligocene to asymmetric in the Miocene. We infer that distinctly asymmetric ice age cycles are not unique to the Late Pleistocene or to extremely large continental ice sheets. The patterns of long-term change in Antarctic climate interpreted from this record are not readily reconciled with existing CO ₂ records.

Few astronomically calibrated high-resolution (≤5 kyr) climate records exist that span the Oligocene–Miocene time interval. Notably, available proxy records show responses varying in amplitude at frequencies related to astronomical forcing, and the main pacemakers of global change on astronomical time-scales remain debated. Here we present newly generated X-ray fluorescence core scanning and benthic foraminiferal stable oxygen and carbon isotope records from Ocean Drilling Program Site 1264 (Walvis Ridge, southeastern Atlantic Ocean). Complemented by data from nearby Site 1265, the Site 1264 benthic stable isotope records span a continuous ∼13-Myr interval of the Oligo-Miocene (30.1–17.1 Ma) at high resolution (∼3.0 kyr). Spectral analyses in the stratigraphic depth domain indicate that the largest amplitude variability of all proxy records is associated with periods of ∼3.4 m and ∼0.9 m, which correspond to 405- and ∼110-kyr eccentricity, using a magnetobiostratigraphic age model. Maxima in CaCO3 content, δ18O and δ13C are interpreted to coincide with ∼110 kyr eccentricity minima. The strong expression of these cycles in combination with the weakness of the precession- and obliquity-related signals allow construction of an astronomical age model that is solely based on tuning the CaCO3 content to the nominal (La2011_ecc3L) eccentricity solution. Very long-period eccentricity maxima (∼2.4-Myr) are marked by recurrent episodes of high-amplitude ∼110-kyr δ18O cycles at Walvis Ridge, indicating greater sensitivity of the climate/cryosphere system to short eccentricity modulation of climatic precession. In contrast, the responses of the global (high-latitude) climate system, cryosphere, and carbon cycle to the 405-kyr cycle, as expressed in benthic δ18O and especially δ13C signals, are more pronounced during ∼2.4-Myr minima. The relationship between the recurrent episodes of high-amplitude ∼110-kyr δ18O cycles and the ∼1.2-Myr amplitude modulation of obliquity is not consistent through the Oligo-Miocene. Identification of these recurrent episodes at Walvis Ridge, and their pacing by the ∼2.4-Myr eccentricity cycle, revises the current understanding of the main climate events of the Oligo-Miocene

The oceans at the time of the Cenomanian–Turonian transition were abruptly perturbed by a period of bottom-water anoxia. This led to the brief but widespread deposition of black organic-rich shales, such as the Livello Bonarelli in the Umbria–Marche Basin (Italy). Despite intensive studies, the origin and exact timing of this event are still debated. In this study, we assess leading hypotheses about the inception of oceanic anoxia in the Late Cretaceous greenhouse world by providing a 6 Myr long astronomically tuned timescale across the Cenomanian–Turonian boundary. We procure insights into the relationship between orbital forcing and the Late Cretaceous carbon cycle by deciphering the imprint of astronomical cycles on lithologic, physical properties, and stable isotope records, obtained from the Bottaccione, Contessa and Furlo sections in the Umbria–Marche Basin. The deposition of black shales and cherts, as well as the onset of oceanic anoxia, is related to maxima in the 405 kyr cycle of eccentricity-modulated precession. Correlation to radioisotopic ages from the Western Interior (USA) provides unprecedented age control for the studied Italian successions. The most likely tuned age for the base of the Livello Bonarelli is 94.17 ± 0.15 Ma (tuning 1); however, a 405 kyr older age cannot be excluded (tuning 2) due to uncertainties in stratigraphic correlation, radioisotopic dating, and orbital configuration. Our cyclostratigraphic framework suggests that the exact timing of major carbon cycle perturbations during the Cretaceous may be linked to increased variability in seasonality (i.e. a 405 kyr eccentricity maximum) after the prolonged avoidance of seasonal extremes (i.e. a 2.4 Myr eccentricity minimum). Volcanism is probably the ultimate driver of oceanic anoxia, but orbital periodicities determine the exact timing of carbon cycle perturbations in the Late Cretaceous. This unites two leading hypotheses about the inception of oceanic anoxia in the Late Cretaceous greenhouse world.