The PVA/PVP, PVA/PVP with 5% and 10% chitosan and PVA/PVP-Iodine fibers were produced via electrospinning technique. Their morphological and chemical characteristics were examined with SEM, TGA, FT-IR, viscometer and four-point probe conductivity measurement apparatus. The addition of chitosan increased the viscosity and the electrical conductivity of the polymer. The increase chitosan contents resulted in the diameters of the fibers smaller than expected. This was attributed to the increase in the viscosity of the solution and the electrical conductivity of the resulting fibers. The DSC results show that iodine was efficiently cross-linked with the polymer, forming an amorphous structure.
29 April 2014 in Polymer-Plastics Technology and Engineering
In this study, PVA/PAA, PVA/PAA/PVP, PVA/PAA/PVP-I and PVA/PAA/PVP/Chitosan fiber mats were prepared via electrospinning. Synthesized nanofibers were characterized by DSC, FT-IR and SEM. DSC results showed that the nanofibers were degraded at 400°C and 450°C. The addition of PVP-K30, PVP-I and chitosan to PVA/PAA structure increased the thermal stability of the nanofibers. SEM micrographs showed that synthesized nanofibers are linear. Fiber diameter measurements showed that average diameters of the fibers are less than 0.5 micron. The average diameters of PVA/PAA, PVA/PAA/PVP, PVA/PAA/PVP-I and PVA/PAA/PVP/Chitosan fibers were calculated as 458 nm, 237 nm, 139 nm, and 270 nm, respectively.
21 November 2011 in Journal of Applied Polymer Science