Rosana Badía Laíño

Dr. Rosana Badía Laíño

Departamento de Química Física y Analítica, Universidad de Oviedo, 33006 Oviedo, Spain
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Research Focus & Metrics

Academic Career Length

15Years (2012-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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19 January 2021 in ACS Sustainable Chemistry & Engineering
Verified
Journal Article
Open access
Clarissa MurruClarissa Murru
Clarissa Murru
RLRosana Badía Laíño
Rosana Badía Laíño
MDMarta E. Díaz-García
Marta E. Díaz-García
Lipids are widely distributed in nature and are one of the most important components of natural foods, synthetic compounds, and emulsions. To date, there is a strong social demand in the industrial sector for the use of sustainable products with a minimal environmental impact. Depending on their origin and composition, lipids can be employed as a plausible alternative as biodegradable lubricants in order to reduce the use of conventional mineral oil lubricants and mitigate their environmental impact. This perspective provides an overview of the advantages and constrains of vegetal oils under different lubrication regimes and the tribochemical reactions that can take place. Also, the different factors and pathways that influence their oxidation, the key role of moisture, and the changes of physical properties under pressure and temperature are reviewed. Special emphasis is devoted to the oxidation instability of fatty acids and vegetal oils and the physical and chemical approaches to improve oxidative and thermal stability are described in detail.

19 November 2020 in Antioxidants
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Journal Article
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MCMurru Clarissa
Murru Clarissa
RLRosana Badía Laíño
Rosana Badía Laíño
MDMarta Elena Díaz-García
Marta Elena Díaz-García
Carbon dots (CDs) due to their unique optical features, chemical stability and low environmental hazard are applied in different fields such as metal ion sensing, photo-catalysis, bio-imaging and tribology, among others. The aims of the present research were to obtain CDs from vegetable wastes (tea and grapes) as carbon sources and to explore their potential properties as radical scavengers. CDs from glutathione/citric acid (GCDs) were synthetized for comparison purposes. The CDs were investigated for their chemical structure, morphology, optical and electronical properties. The antioxidant activity has been explored by DPPH and Folin-Ciocelteau assays in aqueous media. Due to their solubility in oil, the CDs prepared from tea wastes and GCDs were assayed as antioxidants in a mineral oil lubricant by potentiometric determination of the peroxide value. CDs from tea wastes and GCDs exhibited good antioxidant properties both in aqueous and oil media. Possible mechanisms, such as C-addition to double bonds, H-abstraction and SOMO-CDs conduction band interaction, were proposed for the CDs radical scavenging activity. CDs from natural sources open new application pathways as antioxidant green additives.

1 January 2015 in Talanta
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Journal Article
Closed access
GAGaber Hashem Gaber Ahmed
Gaber Hashem Gaber Ahmed
RLRosana Badía Laíño
Rosana Badía Laíño
JCJosefa Angela García Calzón
Josefa Angela García Calzón
MDMarta Elena Díaz-García
Marta Elena Díaz-García

5 June 2014 in Microchimica Acta
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Journal Article
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GAGaber Hashem Gaber Ahmed
Gaber Hashem Gaber Ahmed
RLRosana Badía Laíño
Rosana Badía Laíño
JCJosefa Angela García Calzón
Josefa Angela García Calzón
MDMarta Elena Díaz-García
Marta Elena Díaz-García

13 January 2022 in Applied Sciences
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SRSandra Rodríguez
Sandra Rodríguez
TFTania Fontanil
Tania Fontanil
AOAlvaro J. Obaya
Alvaro J. Obaya
AFAlfonso Fernández-González
Alfonso Fernández-González
MCMurru Clarissa
Murru Clarissa
RLRosana Badía Laíño
Rosana Badía Laíño
Since their discovery in 2004, carbon dots have attracted strong interest in the scientific community due to their characteristic properties, particularly their luminescence and their ease of synthesis and derivatization. Carbon dots can be obtained from different carbon sources, including natural products, resulting in a so-called ’green synthesis’. In this work, we obtain carbon dots from tomato juice in order to obtain nanoparticles with the antioxidant capabilities of the natural antioxidants present in that fruit. The obtained material is characterized regarding nanoparticle size distribution, morphology, surface functional groups and optic properties. Antioxidant properties are also evaluated through the DPPH method and their cytotoxicity is checked against human dermal fibroblast and A549 cell-lines. The results indicate that carbon dots obtained from tomato have a higher antioxidant power than other already-published antioxidant carbon dots. The bandgap of the synthesized materials was also estimated and coherent with the literature values. Moreover, carbon dots obtained from tomato juice are barely toxic for healthy cells up to 72 h, while they induce a certain cytotoxicity in A549 lung carcinoma cells.

22 October 2015 in Science and Technology of Advanced Materials
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Journal Article
Open access
TLTeresa Díaz-Faes López
Teresa Díaz-Faes López
AFAlfonso Fernández-González
Alfonso Fernández-González
ÁRÁngel Del Reguero
Ángel Del Reguero
MMMaría Matos
María Matos
MDMarta Elena Díaz-García
Marta Elena Díaz-García
RLRosana Badía Laíño
Rosana Badía Laíño
Silica nanoparticles (SiO2 NPs) synthesized by the sol–gel approach were engineered for size and surface properties by grafting hydrophobic chains to prevent their aggregation and facilitate their ...