Concentrations of potentially toxic metals including Cd, Cu, Pb, Cr, U, Th in surface water and sediment samples collected from a river were analyzed to assess the contaminations, distribution characteristics, and sources of these metals. The contents of the metals were lower than the standard levels set by World Health Organization (WHO) for drinking water. However, U and Th contents were far beyond the background values of surface water. The concentrations of Cd, Cr, and U in sediments were higher than the background values and the Probable Effect Level (PEL) of sediment quality guidelines (SQGs) which may result in high potential harmful biological effects to aquatic ecosystems. Based on the contamination factor (CF), geo-accumulation index (I_geo), and potential ecological risk index (RI), Cd, Cr, and U were considered to be the metals that mainly contribute to the contamination of sediments. The calculation results also indicated that the sites adjacent to the uranium ore field were highly polluted. Results of cluster analysis, principal component analysis, and correlation analysis revealed that Cr, Pb, U, and Th were highly correlated with each other. These metals mainly originated from both anthropogenic sources and natural processes, especially emissions from uranium mining and quarrying, whereas Cd mostly came from anthropogenic sources (agricultural activities) of the upper reaches of the river.

Anthropogenic activities have had diversiform impacts on the surrounding river and environments. A study on the surface water of the Lhasa River Basin was undertaken to assess its hydrogeochemical characteristics under the influence of anthropogenic activities. A total of 16 samples collected from the Lhasa River were analyzed for pH, electric conductivity (EC), oxidation-reduction potential (ORP), total dissolved solids (TDS), major cations (K⁺, Na⁺, Ca²⁺, and Mg²⁺), major anions (Cl⁻, SO₄²⁻, HCO₃⁻, and NO₃⁻), and trace metals. The pH of the analyzed water samples varied from 6.40 to 9.10, indicating alkaline in nature. The EC values varied from 77.3 to 213 μs/cm while the TDS values varied from 73.37 to 217.55 mg/L. HCO₃⁻ and SO₄²⁻ are the dominant anions while Ca²⁺ and Na⁺ are the dominant cations in the river water. The concentration of alkaline earth metals (Ca²⁺ + Mg²⁺) exceed the alkali metals (Na⁺ + K⁺) and HCO₃⁻ dominates over SO₄²⁻ + Cl⁻ concentrations in the majority of the surface water samples. Ca²⁺-Mg²⁺-HCO₃⁻ and Ca²⁺-Mg²⁺-Cl⁻ are the dominant hydrogeochemical facies in the surface water of the area. The water chemistry is mainly controlled by rock weathering with secondary contribution from anthropogenic sources. The content of trace elements in the Lhasa River is low, basically at the natural background value. The high content of individual elements is mainly due to the mineral resource exploitation and geothermal resources in the basin. Countermeasures and attention should be payed to these aspects, such as the construction of water conservancy facilities, urban economic development, the development of mining activities, and sewage and wastewater discharge, so as to protect the water quality and sustainable development of the Lhasa River Basin.