The lithium-ion batteries in the electric vehicles are nonlinear systems with complex electrochemical dynamics, and estimation of battery state-of-charge (SOC) is affected by factors such as environmental temperature and battery current. Considering the above problems, the accurate estimation of battery SOC has always been a difficult and the critical issue of battery management system (BMS). In this paper, the constant phase element (CPE) is introduced to the traditional time domain circuit model by analyzing the electrochemical impedance spectra of lithium-ion batteries. Accordingly, an equivalent circuit model based on electrochemical impedance is constructed by using fractional order theory, which has specific physical significant, leading to the improved estimation accuracy to represent battery voltage. Moreover, the polarization resistance in the model is replaced by Butler-Volmer (BV) equation, which can solve the problem caused by large current and temperature variation during the actual operation of electric vehicles. Next, based on the model, an H∞ observer is designed for battery SOC estimation, and the proposed SOC observer is tested by real-time experimental data of battery. The efficiency of the proposed model and observer are validated by some simulations and experiment tests.

Temperature field control is crucial for the comprehensive performance of Ni-Co-Mn layered cathode material that is the most important part of lithium-ion batteries. Starting from the aspect of a class of distributed parameter systems described by highly dissipative partial differential equations (PDEs), an event-triggered optimal control (ETOC) method based on adaptive dynamic programming (ADP) for the roller kiln temperature field is proposed. First, we formulate the event-triggered control problem of the temperature field under the general framework of PDE systems. Then, an event-triggered condition is designed based on the stability of the closed-loop PDE system, which also guarantees the upper bound of the performance index. Subsequently, ADP technology is adopted to realize the ETOC, where the critic network is employed to approximate the optimal value function. Since the studied system can be regarded as an impulsive dynamic system with flow dynamics and jump dynamics simultaneously, the stability of the impulsive dynamic system combined with the ADP-based closed-loop PDE system is proved. Finally, simulation results on the temperature field verify the effectiveness of the proposed method.