Through new core wettability simulation technology and the single-sided unidirectional imbibition experimental method, the influence of core wettability on oil imbibition characteristics was studied by using artificial cores with wettability index in the range of −0.9~0.95. Results show that for the cores with permeability from ultra-low to medium–high, the imbibition time shows a monotonically decreasing law with the increase in the wettability index. In the weak water-wet range, the imbibition time increases significantly with the weakening of water-wet. Oil imbibition rate goes up with the increase in wettability index. In the strong water-wet range, the imbibition rate will change significantly with wettability. In the water-wet zone, there is a positive correlation between imbibition oil limit recovery and wettability index, according to which a power exponent model of them is established. The imbibition–displacement ratio, which characterizes the contribution rate of oil recovery by imbibition to that by waterflooding, is also positively correlated with the wettability index. In addition, imbibition–displacement ratios of extra-low permeability cores are very close to that of medium–high permeability cores. According to the analysis of the research results, compared with the strongly water-wet oil layer, the weakly water-wet oil layer with a wettability index of 0–0.5 has a greater contribution to oil recovery by using the enhanced imbibition method.

A novel activators regenerated by electron transfer (ARGET) atom transfer radical polymerization (ATRP) initiation system composing of an initiator sodium chloroacetate, a catalyst ferric chloride, and a reducing agent ascorbic acid was developed to improve the gelation time of the in situ crosslinked polymer system. The kinetics of polymerization of acrylamide showed features of a living/controlled process in which the concentrations of the growing radicals [P·] are kept constant throughout the polymerization process. Compared with conventional potassium persulfate initiators, the gelation time of the in situ crosslinked polymer system can be improved to 40 h or even longer using the ARGET ATRP initiation system at 80 °C due to the low radical concentration and slow polymerization reaction. Core flooding test showed that the ARGET ATRP initiating system developed could initiate the polymerization reaction of the in situ crosslinked polymer system in the core. However, the gelation time was extended in comparison to that of the result obtained in the bottle, resulting from the dilution and adsorption of ARGET ATRP components during the injection process. The research expands the application field of the ARGET ATRP principle and has a promising prospect on controlling the gelation time of the in situ crosslinked polymer system. © 2020 Wiley Periodicals, Inc. J. Polym. Sci. 2020, 58, 519–527