Roger Thomas François Fréty

Dr. Roger Thomas François Fréty

orcid

Research Focus & Metrics

Academic Career Length

52Years (1975-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

View All Publications
1 January 1994 in Journal of the Chemical Society, Faraday Transactions
Verified
Journal Article
Closed access
PDF file
VPVincent Perrichon
Vincent Perrichon
ALAhmidou Laachir
Ahmidou Laachir
GBGérard Bergeret
Gérard Bergeret
RFRoger Thomas François Fréty
Roger Thomas François Fréty
LTLouise Tournayan
Louise Tournayan
OTOlivier Touret
Olivier Touret
Successive reduction steps of CeO2 particles by hydrogen between 300 and 1070 K have been followed by temperature-programmed reduction (TPR) and in situ magnetic measurements on several samples with different BET surface areas. The nature of the phases present in cerias reduced between 670 and 1270 K was determined by X-ray analysis. Finally, reoxidation by oxygen or air was studied at room temperature for all the reduced samples. Magnetic and TPR results show a direct relationship between the degree of reduction and the BET surface area. Indeed, for most of the samples, the degree of reduction at 620–670 K determined by magnetism corresponded to the creation of one layer of Ce3+ ions at the surface of the ceria. A similar relationship between the BET surface area and the extent of reduction was established using the area of the low-temperature TPR composite peak, the maximum of which was found to be constant at 810 K. When the reduction progresses further into the bulk, two main phases were evidenced: first, and expanded cubic CeO2 –x phase derived from the initial ceria by a dilatation of the whole structure and, for deeply reduced samples, the hexagonal Ce2O3 phase. A new intermediate phase, cubic Ce2O3, was also observed on samples reduced at 1070–1170 K. Complete reoxidation by oxygen occurs at room temperature, for all reduction percentages below ca. 60 %, i.e. as long as the reduced phase remained in the cubic form. When the hexagonal Ce2O3 phase has been formed, the reoxidation cannot be completed at 294 K.

1 June 1989 in Catalysis Today
Verified
Journal Article
Closed access
JGJ. Gusmão
J. Gusmão
DBD. Brodzki
D. Brodzki
GDG. Djéga-Mariadassou
G. Djéga-Mariadassou
RFRoger Thomas François Fréty
Roger Thomas François Fréty

31 December 1988 in Catalysis Today
Verified
Journal Article
Closed access
MBMichèle Breysse
Michèle Breysse
MCMartine Cattenot
Martine Cattenot
TDThierry Decamp
Thierry Decamp
RFRoger Thomas François Fréty
Roger Thomas François Fréty
CGChristian Gachet
Christian Gachet
JDJean Claude Duchet
Jean Claude Duchet

29 October 1991 in Applied Catalysis
Verified
Journal Article
Closed access
FNFabio B. Noronha
Fabio B. Noronha
MSMartin Schmal
Martin Schmal
MPMichel Primet
Michel Primet
RFRoger Thomas François Fréty
Roger Thomas François Fréty

1 August 1975 in Journal of Catalysis
Verified
Journal Article
Closed access
CBC. Bolivar
C. Bolivar
HCH. Charcosset
H. Charcosset
RFRoger Thomas François Fréty
Roger Thomas François Fréty
MPM. Primet
M. Primet
LTL. Tournayan
L. Tournayan
RMR. Maurel
R. Maurel

1 May 1993 in Applied Catalysis A: General
Verified
Journal Article
Closed access
FZFatima M.Z. Zotin
Fatima M.Z. Zotin
LTLouise Tournayan
Louise Tournayan
JVJean Varloud
Jean Varloud
VPVincent Perrichon
Vincent Perrichon
RFRoger Thomas François Fréty
Roger Thomas François Fréty