A stable photoactive metal–organic framework UiO-66(Zr) sensitized by adsorbed or directly added rhodamine B dye exhibited photocatalytic activity for hydrogen evolution under visible-light illumination (λ ≥ 420 nm). Using Pt as a co-catalyst, the adsorbed and directly added dye extremely enhanced the photocatalytic activity to 30 and 26 times the value afforded by bare Pt@UiO-66(Zr), respectively.

The biotemplating technique is an environmental-protective high-efficiency new technology by which the resulting TiO2 may simultaneously attain the duplication of structure and self-doping elements from biotemplate materials, which is highly desirable for photocatalytic applications. In this paper, aquatic plant leaves—including reed, water hyacinth, and duckweed—were used as both templates and silicon precursors to successfully synthesize biomorphic TiO2/SiO2 composite with mesoporous structures. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, N2 adsorption–desorption, and UV–visible diffuse reflectance spectra were applied to characterize the microstructures of the samples. The results show that all TiO2/SiO2 composites are mainly composed of an anatase phase with mesoporous structure and possess high specific surface area. Compared with commercial Degussa P25 TiO2, all TiO2/SiO2 samples display intensive light-harvesting efficiency, particularly in the visible light range. The activities were evaluated by using gentian violet as a target for photocatalytic degradation experiments under simulated solar irradiation. The TiO2/SiO2 samples templated by reed and water hyacinth leaves exhibit high activity, while the TiO2/SiO2 samples obtained from duckweed are inferior to P25 in the degradation of gentian violet. A synergistic effect of SiO2 incorporation and structural construction through biotemplating is proposed to be beneficial to photocatalytic activity.

In order to further improve the photocatalytic performance of the SiO₂/TiO₂ composite under visible light irradiation, curcumin-doped SiO₂/TiO₂ nanocomposites were synthesized via directly incorporating it into the structure of SiO₂/TiO₂ during the synthesis using an inexpensive and readily available natural pigment (curcumin) as doping agent. The physicochemical properties of SiO₂/TiO₂ nanocomposites were characterized in detail by X-ray diffraction, transmission electron microscopy, Fourier transform-infrared spectroscopy, N₂ adsorption–desorption isotherms, X-ray photoelectron spectroscopy, and UV-vis diffuse reflectance spectroscopy. The results indicate that all SiO₂/TiO₂ nanocomposites exhibited an anatase phase with a typical mesoporous structure. It was found that the dope of curcumin in the SiO₂/TiO₂ composite could decrease the crystal size, slightly improve the specific surface areas, significantly enhance the visible light absorption, and effectively narrow the band gap energy from 3.04 to 10(eV). Compared with bare SiO₂/TiO₂, the curcumin-doped SiO₂/TiO₂ resulted in enhanced photocatalytic reduction activity for Cr(VI) under visible light irradiation, and the CTS (12) sample with the appropriate content of curcumin of 12 wt % shows the photocatalytic yield reaching 100% within 2.5 hours, which is larger than CT (12) without silica. This could be attributed to the curcumin doping and the synergetic effects of SiO₂ and TiO₂ in SiO₂/TiO₂ nanocomposites.