Metal−organic framework (MOF) UiO‐66/graphitic carbon nitride (g‐C₃N₄) hybrids show enhanced photoactivity for hydrogen evolution using visible light. The efficient charge transfer from photoexcited g‐C₃N₄ to UiO‐66 MOF is responsible for the enhancement in photocatalytic hydrogen production. The qusi‐polymeric nature of the present hybrids makes MOFs a potential candidate to construct active photocatalysts.