There is currently some controversy in the scientific community regarding the efficiency of the water–rock interaction process in the contamination of radon in groundwater. In this study, some difficulties were found in the sampling phase. Many of the water collection points are used for human consumption. As such, some municipalities did not want to collaborate. When this natural contaminant is undetectable to the human sense and may cause pulmonary neoplasms in the long term, it is difficult to obtain collaboration from the municipalities concerned. To overcome this controversy, it is important to understand that geogenic, climatic, hydrological, and topographic features may contribute to the effective transfer of radon from rocks to groundwater. In brief, this new approach combines the radon transfer from the geological substrate to the groundwater circulation through hierarchic agglomerative clustering (HAC) and partial least squares-path modeling (PLS-PM) methods. The results show that some lithologies with higher radon production may not always contribute to noticeable groundwater contamination. In this group, the high-fracturing density confirms the recharge efficiency, and the physical-chemical properties of the hydraulic environment (electric conductivity) plays the main role of radon unavailability in the water intended for human consumption. Besides, the hydraulic turnover time of the springs can be considered an excellent radiological indicator in groundwater. In the absence of an anomalous radioactive source near the surface, it means that the high-turnover time of the springs leads to a low-radon concentration in the water. Besides linking high-risk areas with a short period required to free local flow discharges, this study exposes the virtues of a new perspective of a groundwater contamination risk modeling.

In general, this study was developed to assess the radon contamination in groundwater intended for human consumption, to raise awareness among policy-makers to implement a legal framework for drinking water management and the radiological protection of groundwater resources. Thus, we analyzed with parallel coordinate visualization (PCV) plots what features may influence the water–rock interaction and promote high-radon concentrations in water intended for human consumption. The results show that in granitic areas composed by biotite granites (Group V), although there is a higher radon production in the rocks, the radon transfer to groundwater was not effective, mainly due to the physical and chemical properties of the water. The main conclusions show that in all springs sampled (n = 69) for the entire study area, there are only four springs that must have an immediate intervention, and 22 of them are above the limit imposed by the Portuguese legislation. These results are intended to promote a Portuguese Action Plan for Radon that can be framed in the guidelines on the management and protection of groundwater resources.