Glyphosate is one of the most widely used non-selective systemic herbicides, but nowadays its application is controversially discussed. Optical remote sensing techniques might provide a sufficient tool for monitoring glyphosate use. In order to investigate the potential of this technology, a laboratory experiment was set-up using pots with rolled grass sods. Glyphosate-treated plants were compared to drought-stressed and control plants. All pots were frequently measured using a field spectrometer and a hyperspectral-imaging camera. Plant samples were analysed for photosynthetic pigments, polyphenols and dry matter content. Eight selected vegetation indices were calculated from the spectral measurements. The results show that photosynthetic pigments were sensitive to differentiate between control and glyphosate treated plants already 2 days after application. From the vegetation indices, the normalized difference lignin index (NDLI) responded most sensitively followed by indices referring to photosynthetic pigments, namely, the carotenoid reflectance index (CRI-1) and the photochemical reflectance index (PRI). It can be concluded that spectral vegetation indices are, in principal, a suitable proxy to non-destructively monitor glyphosate application on agricultural fields. Further research is needed to verify its applicability under field conditions. An operational monitoring is, however, currently limited by the requirements for temporal and spectral resolution of the satellite sensors.
The accumulation of microplastics (MPs) in soil and sediments may influence the penetration of contaminants into subsurface environments. However, little attention has been paid to comparing the different roles of two common polyethylene (PE) types—low-density polyethylene (LDPE) and high-density polyethylene (HDPE). In this study, the transport behaviors of tetracycline in saturated quartz sand columns in the presence and absence of these two MPs were investigated, respectively. The results showed that both types of PE MPs restrained the mobility of tetracycline at neutral conditions, while such detrimental effects were weak at acid and alkaline conditions. The degree of nonequilibrium adsorption was higher, and tetracycline transferred easier to the kinetic site for the existence of LDPE than of HDPE. The increased roughness and Brunauer-Emmett-Teller (BET) surface areas, more negative zeta potentials and the formation of oxygen function groups on the surface of MPs after UV-weathering intensified the retardation of tetracycline transport. This study revealed that the PE type and weathering should be taken into account in risk assessment, along with the solution chemistry.