The occurrence of deep-sea ferromanganese nodules and crusts on the seafloor is widespread, providing an important resource for numerous metals such as Ni, Co, and Cu. Although they have been intensively studied in the past, the formation of micro-manganese nodules within carbonate rocks has received less attention, despite the considerable amounts of manganese released from the dissolution of the calcareous framework. The micro-petrographic and geochemical characteristics of reef carbonate rocks recovered from the Zhaoshu plateau in the Xisha uplift, north of the South China Sea, were studied using optical microscopy, scanning electron microscopy, confocal Raman spectrometry, and an electron probe micro-analyzer. The carbonate rocks are composed of biogenic debris, including frameworks of coralline algae and chambers of foraminifer, both of which are suffering strong micritization. Within the calcite micrite, numerous micro-manganese nodules were identified with laminated patterns. Mineral and elemental evidence showed that the Mn oxides in the carbonates are mixed with 10 Å vernadite, 7 Å vernadite and todorokite, both of which are closely associated with the carbonate matrix. The micro-nodules were found to have high Mn/Fe ratios, enriched in Ni and Cu and depleted in Co. We infer that theses nodules are mixed type with early diagenetic growth under oxic–suboxic conditions. The re-distribution of manganite within the rocks is likely influenced by micritization of the calcareous framework. We deduce that microbial-associated reduction of manganite induces the formation of diagenetic todorokite similar to nodules buried in marine sediments.

Sub-bottom profiling traditionally uses low-frequency signals (less than 20 kHz) to examine layered structures of the bottom sediment in large depth, but it has some limitations in deep-sea surveying. The surficial sediment within several meters under the water–sediment boundary in the deep sea cannot be distinguished clearly. In this study, a high-frequency sub-bottom profiler (HFSBP) was developed and applied to a manned deep-submergence vehicle (DSV), named Deep-Sea Warrior, to obtain a centimeter-level resolution stratum of several meters in the deep-sea surficial sediment. Twelve diving tests were carried out, the diversity of surficial benthic profiles on the northern slopes of the South China Sea was shown up for the first time and as many as four layers profiles were obtained in the low bending canyon region, rock surface profiles, discontinuous stratum structures and thick surficial sediment in the deeper region. Continuous and clear stratum structures within a range of about 2 m on the seabed surface sediment were obtained in 11 of the 12 dives. As the dive sites took a certain dispersive distribution, it reflected that the stratum structure of surficial sediment was prevalent in the northern slopes area of the South China Sea for the most part. To verify the effectiveness of HFSBP, a laboratory test in an anechoic tank was performed, and the experiment results verified the layered ability and the thickness measurement stability of it. The comparison was performed with shipboard data of deep-sea sub-bottom profiler (SBP) Bathy-2010, and the HFSBP results were obviously better than those of Bathy-2010 measurement. The clear and continuous fine layered data obtained by HFSBP may help scientists in new area research in marine geophysics.

This paper proposed a compact design of the subsea cobalt-rich crust mining vehicle with a general purpose support vessel for subsea resource exploration, sample collection, and research. The necessary functions were considered in the concept design, including walk, crushing/mining, sample collection, cutter head adaptation, vehicle orientation, crust texture measurement, awareness, positioning, and navigation. The prototype was tested in both tank and subsea environment. The sea trials were carried out with the support of a general purpose support vessel. The track design worked well in both the tank and subsea environment and the mining vehicle walked smoothly in the sea trial. The crust was crushed to the size of 2 mm and 10 mm with different cutting parameters and successfully collected by the jet pump, 6 kg in total. The crust texture was measured by the onboard sonar successfully and can be used for cutting parameter selection. The cameras captured the images of the subsea environment, but the actions of crushing and sample collection produced plumes, which blocked the camera vision. In the situation, the front image sonar can be used to keep the vehicle away from big rocks. The mining vehicle is not limited to the mining and sampling of subsea cobalt-rich crust. Most of the subsea solid resources on the seabed can be considered to use the compact mining vehicle for sampling and related research. The only issues to be considered are the crushing ability and sample size required.

We developed a high-frequency submersible sub-bottom profiler (HF-SSBP) instrument for taking deep-sea sediment measurement. In order to evaluate the reliability of profile data, a laboratory calibration method (LCM) was developed using illuminated acrylic standard boards in anechoic tank to form multi-layer reflections and evaluate the errors of the HF-SSBP. Two layer reflections induced by single boards in different thicknesses and ranges were performed and recorded, after which four layer reflections induced by two boards with an adjusted water crack were set and logged. The results showed that the HF-SSBP resolution was 44.9 mm in acrylic and its equivalent in the sediment was 28.5 mm. The absolute measure error was 7 mm with an acrylic board thickness of 100 mm, and the maximum measure error was 3.5 mm in different water thicknesses. As a test and application, deep-sea sediment measurement of the HF-SSBP was launched and compared with in situ sampling cores in the same site. The measurement thickness for sections A and B are 39.4 cm and 23.2 cm, respectively, corresponding to the sampling core of 39.8 cm and 23.7 cm. The two results are close as we expected. This work demonstrates the reliability and accuracy of the HF-SSBP measurement, thus providing a good choice for deep-sea submergence vehicles to carry this sonar instrument to obtain high-resolution stratum in deep-sea surficial sediments.