Igor Shchetinin

Dr. Igor Shchetinin

orcid

Research Focus & Metrics

Academic Career Length

17Years (2010-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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22 February 2023 in Nanomaterials
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TNTimur Nizamov
Timur Nizamov
Abdulkarim AmirovAbdulkarim Amirov
Abdulkarim Amirov
TKTatiana O. Kuznetsova
Tatiana O. Kuznetsova
IDIrina V. Dorofievich
Irina V. Dorofievich
IBIgor Bordyuzhin
Igor Bordyuzhin
AMAlexander G. Majouga
Alexander G. Majouga
Nowadays, magnetoelectric nanomaterials are on their way to finding wide applications in biomedicine for various cancer and neurological disease treatment, which is mainly restricted by their relatively high toxicity and complex synthesis. This study for the first time reports novel magnetoelectric nanocomposites of CoxFe3−xO4-BaTiO3 series with tuned magnetic phase structures, which were synthesized via a two-step chemical approach in polyol media. The magnetic CoxFe3−xO4 phases with x = 0.0, 0.5, and 1.0 were obtained by thermal decomposition in triethylene glycol media. The magnetoelectric nanocomposites were synthesized by the decomposition of barium titanate precursors in the presence of a magnetic phase under solvothermal conditions and subsequent annealing at 700 °C. X-ray diffraction revealed the presence of both spinel and perovskite phases after annealing with average crystallite sizes in the range of 9.0–14.5 nm. Transmission electron microscopy data showed two-phase composite nanostructures consisting of ferrites and barium titanate. The presence of interfacial connections between magnetic and ferroelectric phases was confirmed by high-resolution transmission electron microscopy. Magnetization data showed expected ferrimagnetic behavior and σs decrease after the nanocomposite formation. Magnetoelectric coefficient measurements after the annealing showed non-linear change with a maximum of 89 mV/cm*Oe with x = 0.5, 74 mV/cm*Oe with x = 0, and a minimum of 50 mV/cm*Oe with x = 0.0 core composition, that corresponds with the coercive force of the nanocomposites: 240 Oe, 89 Oe and 36 Oe, respectively. The obtained nanocomposites show low toxicity in the whole studied concentration range of 25–400 μg/mL on CT-26 cancer cells. The synthesized nanocomposites show low cytotoxicity and high magnetoelectric effects, therefore they can find wide applications in biomedicine.

10 October 2020 in Crystals
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Boris B StraumalBoris B Straumal
Boris B Straumal
NMNatalia S. Martynenko
Natalia S. Martynenko
DTDiana Temralieva
Diana Temralieva
VSVladimir Serebryany
Vladimir Serebryany
NTNataliya Tabachkova
Nataliya Tabachkova
JEJuri Estrin
Juri Estrin
The effect of equal channel angular pressing (ECAP) on the microstructure, texture, mechanical properties, and corrosion resistance of the alloys Mg-6.0%Ag and Mg-10.0%Gd was studied. It was shown that ECAP leads to grain refinement of the alloys down to the average grain size of 2–3 μm and 1–2 μm, respectively. In addition, in both alloys the precipitation of fine particles of phases Mg54Ag17 and Mg5Gd with sizes of ~500–600 and ~400–500 nm and a volume fraction of ~9% and ~8.6%, respectively, was observed. In the case of the alloy Mg-6.0%Ag, despite a significant grain refinement, a drop in the strength characteristics and a nearly twofold increase in ductility (up to ~30%) was found. This behavior is associated with the formation of a sharp inclined basal texture. For alloy Mg-10.0%Gd, both ductility and strength were enhanced, which can be associated with the combined effect of significant grain refinement and an increased probability of prismatic and basal glide. ECAP was also shown to cause a substantial rise of the biodegradation rate of both alloys and an increase in pitting corrosion. The latter effect is attributed to an increase in the dislocation density induced by ECAP and the occurrence of micro-galvanic corrosion at the matrix/particle interfaces.

30 December 2022 in Materials
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PNPolina Igorevna Nikolenko
Polina Igorevna Nikolenko
TNTimur Nizamov
Timur Nizamov
IBIgor Bordyuzhin
Igor Bordyuzhin
Maxim AbakumovMaxim Abakumov
Maxim Abakumov
YBYulia A. Baranova
Yulia A. Baranova
ISIgor Shchetinin
Igor Shchetinin
In this work, complex studies of the structure and magnetic properties of SrFe12−xInxO19 powders obtained by the mechanochemical and citrate methods were carried out. The solubility of In in strontium hexaferrite SrFe₁₂O₁₉ at 1200 °C was determined. The structure and properties of the powders were studied using X-ray diffraction analysis, Mössbauer spectroscopy and scanning electron microscopy. Measurements of magnetic properties in magnetic fields up to 1600 kA/m were also performed. Additionally, the hyperthermia effect was investigated. The possibility of controlling the coercivity of the samples in the range from 188.9 kA/m to 22.3 kA/m and saturation magnetization from 63.5 A·m2/kg to 44.2 A·m2/kg with an increase in the degree of In doping was also demonstrated. Investigation of the magnetic hyperthermia of the samples was carried out by temperature measurement with an IR camera when they were introduced into alternating magnetic fields of various frequencies (144, 261 and 508 kHz) and amplitudes (between 11.96 and 19.94 kA/m). According to the study result, there was detected the heating of the SrFe12−xInxO19 sample (x = 1.7). The highest values of magnetic hyperthermia of the sample were observed in a 19.94 kA/m magnetic field and a frequency of 261 kHz. At a concentration of 56.67 g/L, the sample was heated from 23 to 41 °C within 2 min. The parameters SLP (specific loss power) and ILP (intrinsic loss power) were calculated.

5 March 2022 in Sensors
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ABAnusha Bhat
Anusha Bhat
AAAninamol Ani
Aninamol Ani
P. PoorneshP. Poornesh
P. Poornesh
AAAlbin Antony
Albin Antony
BHBhaghyesh
Bhaghyesh
Vinaya kumar Kadayra BasavarajappaVinaya kumar Kadayra Basavarajappa
Vinaya kumar Kadayra Basavarajappa
Ag-doped WO3 (Ag–WO3) films were deposited on a soda-lime glass substrate via a facile spray pyrolysis technique. The surface roughness of the films varied between 0.6 nm and 4.3 nm, as verified by the Atomic Force Microscopy (AFM) studies. Ammonia (NH3)-sensing measurements of the films were performed for various concentrations at an optimum sensor working temperature of 200 °C. Enrichment of oxygen vacancies confirmed by X-ray Photoelectron Spectroscopy (XPS) in 1% Ag–WO3 enhanced the sensor response from 1.06 to 3.29, approximately 3 times higher than that of undoped WO3. Limit of detection (LOD) up to 500 ppb is achieved for 1% Ag–WO3, substantiating the role of Ag in improving sensor performance.

1 October 2020 in Physical Review B
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SGS. Yu. Grebenchuk
S. Yu. Grebenchuk
ZDZh. A. Devizorova
Zh. A. Devizorova
IGIgor A Golovchanskiy
Igor A Golovchanskiy
ISIgor Shchetinin
Igor Shchetinin
GCG.-H. Cao
G.-H. Cao
VSVasliy Stolyarov
Vasliy Stolyarov
In P-doped pnictide, EuFe2(As1−xPx)2 superconductivity coexists with a ferromagnetism of Eu−4f spins. Above x≃0.26, superconductivity vanishes whereas ferromagnetism remains. Here, we focus on the crossover region and study two EuFe2(As1−xPx)2 single crystals with x=0.21 and x=0.25; the superconducting critical temperature of the first one is slightly higher and of the second one is slightly lower than the Curie temperature. Despite similar compositions, characteristic temperatures and bulk magnetic properties of the two systems, their local magnetic structures and superconducting vortex-antivortex phases are found drastically different. We demonstrate that the interplay between superconductivity and magnetism is strongly dominated by the superconducting order in the first system, whereas it is mainly governed by ferromagnetism in the second one. Our discovery raises several fundamental questions on the vortex nucleation and dynamics in magnetic superconductors.

24 November 2023 in Ceramics International
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VPVictor V. Popov
Victor V. Popov
AMAlexey P. Menushenkov
Alexey P. Menushenkov
AYA.A. Yastrebtsev
A.A. Yastrebtsev
Yan V. ZubavichusYan V. Zubavichus
Yan V. Zubavichus
BGB.R. Gaynanov
B.R. Gaynanov
OSO.N. Seregina
O.N. Seregina