Optical textures and appropriate orientational structures have been studied within droplets of chiral nematic dispersed in polymer assigning the homeotropic anchoring. The helix axis of the chiral structure inside droplets forms the bipolar configuration. The optical droplet textures were analysed in the unpolarised light, analyser switching-off scheme and in crossed polarisers. The twisted loop defect reveals itself convincingly in all schemes. Its appearance at the optical patterns of the chiral nematic droplets has been examined depending on their size and the aspect direction. The existence of the defect has been verified by the structural and optical calculations. The effect of an electric field on both the defect line shape and the orientational structure of chiral nematic has been studied.
The films of a polymer-dispersed nematic liquid crystal doped with an ionic surfactant were studied. The surface-anchoring modification effect caused by the local increase in the concentration of surface-active ions was observed at the polymer-liquid crystal interface under the action of an electric field. The modification of the boundary conditions leads to the transformation of the orientational structure of the nematic droplets and, as a result, to an appreciable change in their texture patterns and light-scattering efficiency at the interfaces. The monopolar director configurations (normal and curved) arising in the process of orientational structure transformations are considered and their typical textures are demonstrated. The possibility that the monopolar structure can be formed is theoretically substantiated by the computer simulation of the director field in a nematic droplet with the boundary conditions corresponding to the experiment.
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The electro-optical properties of polymer dispersed liquid crystal (PDLC) films are highly dependent on the features of the contained liquid crystal (LC) droplets. Cholesteric LC droplets with homeotropic boundaries can form several topologically different orientational structures, including ones with single and more point defects, layer-like, and axisymmetric twisted toroidal structures. These structures are very sensitive to an applied electric field. In this work, we have demonstrated experimentally and by computer simulations that twisted toroidal droplets reveal strong structural response to the electric field. In turn, this leads to vivid changes in the optical texture in crossed polarizers. The response of droplets of different sizes were found to be equivalent in terms of dimensionless parameters. In addition, the explanation of this phenomenon showed a comparison of theoretical and experimental structural response curves aids to determine the shape of the droplet. Finally, we demonstrated that the addition of a dichroic dye allows such films to be used as optical filters with adjustable color even without polarizers.
1 July 2016 in Journal of Quantitative Spectroscopy and Radiative Transfer
It was found that the effect of the ionic modification of anchoring in liquid-crystal droplets can be implemented in the inverse regime. Droplets of 4-n-pentyl-4′-cyanobiphenyl nematic doped with ionic cetyltrimethylammonium bromide surfactant were dispersed in polyvinyl alcohol and investigated. In the initial state, nematic droplets have a radial structure with homogeneous homeotropic anchoring typical of the surfactant used. In the presence of a dc electric field, the boundary conditions become tangential in the surface area left by the cations. That results in the transformation of an orientational structure following by various scenarios. For the new states of nematic droplets, the distribution of the director field was analyzed and the corresponding textural patterns were numerically calculated.