A ureido-pyrimidinone (UPy)-functionalized poly(acrylic acid) grafted with poly(ethylene glycol)(PEG), designated PAU-g-PEG, was developed as a high performance polymer binder for Si anodes in lithium-ion batteries. By introducing both a ureido-pyrimidinone (UPy) unit, which is capable of self-healing through dynamic hydrogen bonding within molecules as well as with Si, and an ion-conducting PEG onto the side chain of the poly(acrylic acid), this water-based self-healable and conductive polymer binder can effectively accommodate the volume changes of Si, while maintaining electronic integrity, in an electrode during repeated charge/discharge cycles. The Si@PAU-g-PEG electrode retained a high capacity of 1,450.2 mAh g⁻¹ and a Coulombic efficiency of 99.4% even after 350 cycles under a C-rate of 0.5 C. Under a high C-rate of 3 C, an outstanding capacity of 2,500 mAh g⁻¹ was also achieved, thus demonstrating its potential for improving the electrochemical performance of Si anodes.

Comb-shaped poly(arylene ether sulfone)s with pendant alkyl imidazolium groups were developed as anion-exchange membranes (AEMs). The imidazolium-functionalized polymers with relatively long alkyl chains formed self-aggregated structures with large ionic clusters and clear hydrophilic–hydrophobic phase separation. These comb-shaped membranes, with ion-exchange capacities of only 0.92–1.14 meq g⁻¹, showed very high hydroxide conductivities of over 0.03 S cm⁻¹ at 20 °C and 0.14 S cm⁻¹ at 80 °C. Furthermore, the self-aggregated structure resulting from these comb-shaped polymers exhibited excellent thermal, mechanical and dimensional stability, as well as superior chemical stability at high pH.

Mixed matrix membranes (MMMs) have attracted significant attention for overcoming the limitations of traditional polymeric membranes for gas separation through the improvement of both permeability and selectivity. However, the development of defect-free MMMs remains challenging due to the poor compatibility of the metal–organic framework (MOF) with the polymer matrix. Thus, we report a surface-modification strategy for a MOF through grafting of a polymer with intrinsic microporosity onto the surface of UiO-66-NH₂. This method allows us to engineer the MOF–polymer interface in the MMMs using Pebax as a support. The insertion of a PIM structure onto the surface of UiO-66-NH₂ provides additional molecular transport channels and enhances the CO₂ transport by increasing the compatibility between the polymer and fillers for efficient gas separation. As a result, MMM with 1 wt% loading of PIM-grafted-MOF (PIM-g-MOF) exhibited very promising separation performance, with CO₂ permeability of 247 Barrer and CO₂/N₂ selectivity of 56.1, which lies on the 2008 Robeson upper bound. Moreover, this MMM has excellent anti-aging properties for up to 240 days and improved mechanical properties (yield stress of 16.08 MPa, Young’s modulus of 1.61 GPa, and 596.5% elongation at break).