Subsurface contamination by light non-aqueous phase liquids (LNAPL) is a widespread global problem that requires appropriate techniques to remediate soil and groundwater. In this paper, the subsurface transport over multiple phases (STOMP) model was used to simulate LNAPL multiphase flow and transport during multiphase extraction (MPE) application in two Brazilian tropical soils (silty sand and oxisol) contaminated by diesel. The model was applied to a hypothetical contamination site, with the initial LNAPL thickness observed in well extraction. The first part consisted of the MPE system sensitivity analysis, varying the applied vacuum and tip tube position. The Van Genuchten α parameter and hydraulic conductivity were the properties that most affected LNAPL saturation and fluid extraction volumes. Suitable applied vacuum and tip tube position parametrization was imperative for the efficiency of LNAPL extraction. After the definition of an appropriate MPE system configuration, simulations demonstrated that the immobile LNAPL saturation affected fluid extraction and diesel oil concentrations in aqueous and gas saturation. The model applied is able to predict LNAPL contaminant behavior in porous media during MPE technique application.