We report on a novel method to fabricate single, multiple and large-area high-density ensembles of nitrogen vacancy (NV) color centers in synthetic type Ib bulk diamond by femtosecond laser illumination. Electron beams generated in propagation of intense infrared laser pulses in air sputtered on a diamond sample under high temperature aroused by the laser illumination, creating NV color centers. Typical photoluminescence (PL) spectra of NV centers could be observed on the illuminated spots. Photon streams from individual photoluminescent points exhibited anti-bunching effect by the second-order correlation measurement, evidencing single and multiple photon-emitters around the laser illuminated spots.

We demonstrate few-photon-level infrared imaging at 1040 nm by coincidence frequency upconversion with a high conversion efficiency of 33.5%. By synchronous pulse pumping at 1549 nm, the infrared object image was spectrally upconverted into the visible regime. The upconverted image was captured by a silicon electron multiplying charged coupled device without any scanning devices, thus gaining in simplicity and speed. The imaging sensitivity was improved by reducing the background noise with coincidence pulsed pumping at long wavelength.

Ultrasensitive spectroscopy is an essential component in mid-infrared (MIR) technology. However, the drawbacks of MIR detectors pose challenges to robust MIR spectroscopy at the single-photon level. We propose an MIR single-photon frequency upconversion spectroscopy nonlocally mapping the MIR information to the time domain. Broadband MIR photons from spontaneous parametric downconversion are frequency-upconverted to the near-infrared band with quantum correlation preservation. Via the group delay of fiber, the MIR spectral information within a 1.18-micrometer bandwidth of 2.76 to 3.94 micrometers is then successfully projected to arrival times of correlated photon pairs. Under the conditions of 6.4 × 10 ⁶ photons per second illumination, the transmission spectra of polymers with single-photon sensitivity are demonstrated using single-pixel detectors. The developed approach circumvents scanning and frequency selection instability, which stands out for its inherent compatibility for evolving environments and scalability for various wavelengths. Because of its high sensitivity and robustness, characterization of biochemical samples and weak measurement of quantum systems are possible to foresee.

An analogy of electromagnetically induced transparency (EIT) based on all-dielectric metamaterial is theoretically demonstrated in this paper. The U-shaped Silicon-based metamaterial unit cell comprises a dipole antenna supported by one horizontal nanoscale bar and a quadrupolar antenna supported by two vertical nanoscale bars. The near-field coupling between the two antennas and the reduction of absorption loss lead to a narrow EIT-like transmission window with a high quality-factor of 130, which exhibits a refractive index sensitivity with a figure-of-merit of 29. The group delay of 0.75 ps and the group index of 2035 are obtained in the transmission window. Due to these unique optical properties, the proposed metamaterial structure can find many applications including slow-light devices, optical sensors, enhancement of non-linear processes, and storage of quantum information.

We demonstrate efficient single-photon detection at $1.04\mu \text{m}$ with quite low background counts by using the frequency upconversion detection technique with pulsed single-photon source and strong pump field prepared from two synchronized fiber lasers. Temporal and spectral control of the pump and signal lasers enabled an upconversion efficiency of 81.1%. As the system was pumped at a wavelength longer than that of the signal, the corresponding background counts were reduced down to $1.5\times {10}^3{\text{s}}^{-1}$ due to efficient suppression of parametric fluorescence in the periodic poled lithium niobate crystal.

As a non-classical light source, single-photon source plays an essential role in the foundation of quantum physics and has been attracting a lot of attention of researchers over the world. Up to now, among different kinds of single-photon sources, single color centers in the diamond are very outstanding for the stable emission at room temperature as well as the spin controllability at ambient environment. Those color centers in the diamond with excellent properties are usually formed by impurity atoms and lattice vacancies. Nowadays, complex environments are necessary to the preparation of color centers generally. This restricts the research and applications of those color centers to a certain extent. Therefore, to develop efficient and high-precision fabrication methods of single color centers in the diamond at ambient environment is a need. On this condition, femtosecond (fs) laser process, a mature micro-nano processing technology, have been demonstrated to be a feasible, efficient, and fast production of the color centers in the diamond. This review discusses the state of the art in the preparation of single color centers in diamond and their applications in different areas. Graphical abstract