As part of the Zero Pollution Action Plan of the Green Deal, the European Commission has set the goal of reducing the number of premature deaths caused by fine particulate matter (PM2.5) by at least 55% by 2030, compared to 2005 levels. To achieve this, the European Commission aims to introduce stricter limits. In urban areas, road transport is a significant source of PM emissions. Vehicle PM originates from engine exhaust and from tire, brake and road wear, as well as from road dust resuspension. In recent decades, the application of stringent emission limits on vehicle exhaust has led to the adoption of technologies capable of strongly reducing PM emissions at the tailpipe. Further, the progressive electrification of vehicle fleets will lead to near-zero exhaust PM emissions. On the other hand, non-exhaust PM emissions have increased in recent years following the proliferation of sport utility vehicles (SUVs), whose numbers have jumped nearly tenfold globally, and electric vehicles, as these vehicles tend to be heavier than corresponding conventional and older internal combustion engine light-duty vehicles. This shift has resulted in a more modest reduction in PM10 and PM2.5 emissions from the transport sector compared to other pollutants (−49% and −55%, respectively, from 1990 to 2020). This report aims to provide an up-to-date overview of non-exhaust PM characterization, drawing insights from the recent scientific literature to address this critical environmental and public health challenge.

The valorization of residual biomass plays today a decisive role in the concept of “circular economy”, according to which each waste material must be reused to its maximum extent. The collection and energy valorization at the local level of biomass from forest management practices and wildfire prevention cutting can be settled in protected areas to contribute to local decarbonization, by removing power generation from fossil fuels. Despite the evident advantages of bioenergy systems, several problems still hinder their diffusion, such as the need to assure their reliability by extending the operating range with materials of different origin. The Italian project “INNOVARE—Innovative plants for distributed poly-generation by residual biomass”, funded by the Italian Ministry of Economic Development (MISE), has the main scope of improving micro-cogeneration technologies fueled by biomass. A micro-combined heat and power (mCHP) unit was chosen as a case study to discuss pros and cons of biomass-powered cogeneration within a national park, especially due to its flexibility of use. The availability of local biomasses (woodchips, olive milling residuals) was established by studying the agro-industrial production and by identifying forest areas to be properly managed through an approach using a satellite location system based on the microwave technology. A detailed synergic numerical and experimental characterization of the selected cogeneration system was performed in order to identify its main inefficiencies. Improvements of its operation were optimized by acting on the engine control strategy and by also adding a post-treatment system on the engine exhaust gas line. Overall, the electrical output was increased by up to 6% using the correct spark timing, and pollutant emissions were reduced well below the limits allowed by legislation by working with a lean mixture and by adopting an oxidizing catalyst. Finally, the global efficiency of the system increased from 45.8% to 63.2%. The right blending of different biomasses led to an important improvement of the reliability of the entire plant despite using an agrifood residual, such as olive pomace. It was demonstrated that the use of this biomass is feasible if its maximum mass percentage in a wood matrix mixture does not exceed 25%. The project was concluded with a real operation demonstration within a national park in Southern Italy by replacing a diesel genset with the analyzed and improved biomass-powered plant and by proving a decisive improvement of air quality in the real environment during exercise.

A small-scale plant was built for measuring the ability of solid sorbents towards the capture of carbon dioxide (CO₂) in exhaust flue gas from an internal combustion engine. The investigated sorbents were calcium and lithium hydroxides. Both sorbents are low cost and used in the breathing gas purification systems. The carbonation capacity of each sorbent was measured for different sorbent granulometry (pellets and powder), different temperature (from ambient up to 300 °C), gas space velocity, moisture content and chemical composition of the gaseous stream. The aim was, in fact, to expose the sorbents to a gas stream with chemical and physical parameters close to those at the exhaust of an internal combustion engine. Carbonation capacity was measured with a double technique: on-line by continuously CO₂ measurement with a non-dispersive infrared analyzer and off-line by using scanning electron microscopy on carbonated sorbents. Experimental results showed good CO₂ uptake capacity of calcium hydroxide at low temperature (between 20 and 150 °C). Performance improvements came from the fine granulometry due to the increased exposed surface area; moreover, the presence of the moisture in gas stream also enhanced CO₂ capture. The presence of sulphur dioxide and nitric oxide, instead, greatly decreased the carbonation capacity of sorbents.