Rising pollution levels resulting from vehicular emissions and the depletion of petroleum-based fuels have left mankind in pursuit of alternatives. There are stringent regulations around the world to control the particulate matter (PM) emissions from internal combustion engines. To this end, researchers have been exploring different measures to reduce PM emissions such as using modern combustion techniques, after-treatment systems such as diesel particulate filter (DPF) and gasoline particulate filter (GPF), and alternative fuels. Alternative fuels such as biodiesel (derived from edible, nonedible, and waste resources), alcohol fuels (ethanol, n-butanol, and n-pentanol), and fuel additives have been investigated over the last decade. PM characterization and toxicity analysis is still growing as researchers are developing methodologies to reduce particle emissions using various approaches such as fuel modification and after-treatment devices. To address these aspects, this review paper studies the PM characteristics, health issues, PM physical and chemical properties, and the effect of alternative fuels such as biodiesel, alcohol fuels, and oxygenated additives on PM emissions from diesel engines. In addition, the correlation between physical and chemical properties of alternate fuels and the characteristics of PM emissions is explored.

This paper builds on previous work using surrogate fuel to investigate advanced internal combustion engine fuels. To date, a surrogate fuel of this nature has not been used for microalgae hydrothermal liquefaction (HTL) biocrude. This research used five different chemical groups found in microalgae HTL biocrude to design a surrogate fuel. Those five chemical groups constitute around 65% (by weight) of a microalgae biocrude produced by HTL. Weight percentage of the microalgae HTL biocrude chemical compounds were used to design the surrogate fuel, which was miscible with diesel at all percentages. The engine experiments were conducted on a EURO IIIA turbocharged common-rail direct-injection six-cylinder diesel engine to test engine performance and emissions. Exhaust emissions, including particulate matter and other gaseous emissions, were measured with the surrogate fuel and a reference diesel fuel. Experimental results showed that without significantly deteriorating engine performance, lower particulate mass, particulate number and CO emissions were observed with a penalty in NOx emissions for all surrogate blends compared to those of the reference diesel