The performance of a sensor platform for environmental or industrial monitoring is sensitive to the cost and performance of the individual sensor elements. Thus, the detection limits, accuracy, and precision of commercially available, low-cost carbon dioxide and methane gas concentration sensors were evaluated by precise measurements at known gas concentrations. Sensors were selected based on market availability, cost, power consumption, detection range, and accuracy. A specially constructed gas mixing chamber, coupled to a precision bench-top analyzer, was used to characterize each sensor during a controlled exposure to known gas concentrations. For environmental monitoring, the selected carbon dioxide sensors were characterized around 400 ppm. For methane, the sensor response was first monitored at 0 ppm, close to the typical environmental background. The selected sensors were then evaluated at gas concentrations of several thousand ppm. The determined detection limits accuracy, and precision provides a set of matrices that can be used to evaluate and select sensors for integration into a sensor platform for specific applications.
1 May 2014 in Journal of Materials in Civil Engineering
This paper describes the results of an experimental study that uses radio frequency identification (RFID) technology to detect cracking in concrete elements. A RFID-based sensor is used to monitor the change in electrical resistance that occurs in conductive materials applied to the surface of the concrete. When the concrete substrate is strained, the conductive material at the surface is stretched, and its electrical resistance increases. If the concrete substrate is strained to the point where it cracks, the conductive material at the surface also cracks, causing its electrical resistance to increase by orders of magnitude. This paper describes how this increase in electrical resistance attributable to cracking can be detected wirelessly by RFID technology. To experimentally illustrate the application of this technology, an RFID-based sensor and conductive surface materials are used to detect cracking in the restrained ring test. The experimental results indicate that this technology can be easi...
Titanium(IV) solutions are known to detect hydrogen peroxide in solutions by a colorimetric method. Xplosafe’s XploSens PS commercial titanium(IV)-based peroxide detection test strips are used to detect hydrogen peroxide in liquids. The use of these test strips as gas-phase detectors for peroxides was tested using low-cost hardware. The exposure of these strips to hydrogen peroxide liquid or gas leads to the development of an intense yellow color. For liquids, a digital single-lens reflex camera was used to quantify the color change using standardized solutions containing between 50 and 500 ppm peroxide by mass. Analysis of the images with color separation can provide a more quantitative determination than visual comparison to a color chart. For hydrogen peroxide gas, an inexpensive web camera and a tungsten lamp were used to measure the reflected light intensity as a function of exposure from a test strip held in a custom cell. First-order behavior in the color change with time was observed during the exposure to peroxide vapor over a range of peroxide concentrations from 2 and 30 ppm by volume. For a 1-min measurement, the gas-phase detection limit is estimated to be 1 ppm. A 0.01 ppm detection limit can be obtained with a 1-h exposure time. Titanium(IV)-based peroxide detection test strips are sensitive enough to work as a gas-phase hydrogen peroxide detector.
Carbon sequestration and enhanced oil recovery are two important geochemical applications currently deployed using carbon dioxide (CO2), a prevalent greenhouse gas. Despite the push to find ways to use and store excess CO2, the development of a large-area monitoring system is lacking. For these applications, there is little literature reporting the development and testing of sensor systems capable of operating in remote areas without maintenance and having significantly low cost to allow their deployment across a large land area. This paper presents the design and validation of a low-cost solar-power distributed sensing architecture using a wireless mesh network integrated, at selective nodes, into a cellular network. This combination allows an “internet of things” approach in remote locations and the integration of a large number of sensor units to monitor CO2 and methane (CH4). This system will allow efficient large area monitoring of both rare catastrophic leaks along with the common micro-seepage of greenhouse gas near carbon sequestration and oil recovery sites. The deployment and testing of the sensor system was performed in an open field at Oklahoma State University. The two-tear network functionality and robustness were determined from a multi-year field study. The reliability of the system was benchmarked by correlating the measured temperature, pressure, and humidity measurement by the network of devices to existing weather data. The CO2 and CH4 gas concentration tracked their expected daily and seasonal cycles. This multi-year field study established that this system can operate in remote areas with minimal human interactions.
15 July 2003 in The Journal of Physical Chemistry B