Gas exchange across the air-water interface is a critical process that maintains adequate dissolved oxygen (DO) in the water column to support life. Oxygen reaeration rates can be accurately measured using deliberate gas tracers, like sulfur hexafluoride (SF₆) or xenon (Xe). Two continuous release experiments were conducted in different creeks in the Sierra Nevada of California: Sagehen Creek in September, 2009, using SF₆ and Martis Creek in August, 2012, using both SF₆ and Xe. Measuring gas loss along the creek, which was approximated with the one-dimensional advection-dispersion equation, allows for the estimation of the SF₆ or Xe reaeration coefficient (K_SF6, K_Xe), which is converted to DO reaeration (K_DO or K₂) using Schmidt numbers. Mean K_SF6 for upper and lower Sagehen and Martis Creeks were, respectively, 34 day⁻¹, 37 day⁻¹ and 33 day⁻¹, with corresponding K_DOs of 61 day⁻¹, 66 day⁻¹ and 47 day⁻¹. In Martis Creek, K_Xe was slightly higher (21%) than K_SF6, but the calculated K_DO from SF₆ agreed with the calculated K_DO from Xe within about 15%; this difference may be due to bubble-enhanced gas transfer. Established empirical equations of K_DO using stream characteristics did a poor job predicting K_DO for both creeks.

During the dry months of the water year in Mediterranean climates, groundwater influx is essential to perennial streams for sustaining ecosystem health and regulating water temperature. Predicted earlier peak flow due to climate change may result in decreased baseflow and the transformation of perennial streams to intermittent streams. In this study, naturally occurring radon-222 (²²²Rn) was used as a tracer of groundwater influx to Martis Creek, a subalpine stream near Lake Tahoe, CA. Groundwater ²²²Rn is estimated based on measurements of ²²²Rn activity in nearby deep wells and springs. To determine the degassing constant (needed for quantification of water and gas flux), an extrinsic tracer, xenon (Xe), was introduced to the stream and monitored at eight downstream locations. The degassing constant for ²²²Rn is based on the degassing constant for Xe, and was determined to be 1.9–9.0 m/day. Applying a simple model in which stream ²²²Rn activity is a balance between the main ²²²Rn source (groundwater) and sink (volatilization), the influx in reaches of the upstream portion of Martis Creek was calculated to be <1 to 15 m³/day/m, which cumulatively constitutes a significant portion of the stream discharge. Experiments constraining ²²²Rn emanation from hyporheic zone sediments suggest that this should be considered a maximum rate of influx. Groundwater influx is typically difficult to identify and quantify, and the method employed here is useful for identifying locations for focused stream flow measurements, for formulating a water budget, and for quantifying streamwater–groundwater interaction.

Mount Shasta (4322 m) is famous for its spring water. Water for municipal, domestic and industrial use is obtained from local springs and wells, fed by annual snow melt and sustained perennially by the groundwater flow system. We examined geochemical and isotopic tracers in samples from wells and springs on Mount Shasta, at the headwaters of the Sacramento River, in order to better understand the hydrologic system. The topographic relief in the study area imparts robust signatures of recharge elevation to both stable isotopes of the water molecule (δ¹⁸O and δD) and to dissolved noble gases, offering tools to identify recharge areas and delineate groundwater flow paths. Recharge elevations determined using stable isotopes and noble gas recharge temperatures are in close agreement and indicate that most snowmelt infiltrates at elevations between 2000 m and 2900 m, which coincides with areas of thin soils and barren land cover. Large springs in Mt Shasta City discharge at an elevation more than 1600 m lower. High elevation springs (>2000 m) yield very young water (<2 years) while lower elevation wells (1000–1500 m) produce water with a residence time ranging from 6 years to over 60 years, based on observed tritium activities. Upslope movement of the tree line in the identified recharge elevation range due to a warming climate is likely to decrease infiltration and recharge, which will decrease spring discharge and production at wells, albeit with a time lag dependent upon the length of groundwater flow paths.

Water bodies in the East Bay Regional Park District (EBRPD), California, United States, provide aesthetic value and critical ecosystem services, but are often adversely affected by the activities and infrastructure of the intensely urban environment that surrounds the parks. EBRPD leases a golf course (Tilden Golf Course (TGC)) in Tilden Regional Park, one of its most popular parks located in the Berkeley Hills, which was certified as an Audubon Cooperative Sanctuary in 2013. Nonetheless, application of nutrients and pesticides (fungicides, plant growth regulators and herbicides) are commonly used to maintain turf systems and may be transported via surface runoff or through subsurface drainage to surface waters, leading to the concern that golf courses are a major contributor to water pollution. We studied the possible contribution of nutrients (NO₃-N and PO₄-P) and pesticides transported via storm-generated surface runoff and via groundwater from TGC to the primary drainage in the watershed, Wildcat Creek. Lake Anza, a popular open water swimming lake, is located downstream from TGC and experiences occasional nutrient-driven algal blooms that have caused swim beach closures. Measured NO₃-N and PO₄-P in the stream, at times, exceeded concentration limits of 1 mg/L (as N) and 0.05 mg/L (as P), respectively, considered protective of aquatic ecosystems by the United States Environmental Protection Agency (1986). We found that phosphorous likely has a dominant natural source, but nitrogen is primarily derived from a golf course fertilizer source and its concentration increases in the stream during runoff events, while other soluble species decrease. Analyses of pesticides in water reveal the presence of Azoxystrobin in stream water at the golf course, but with concentrations well below the regulatory limit. These results indicate that all other pesticides applied on TGC are not likely transported to the stream, suggesting future reactive transport research must treat contaminant species independently based on their specific transport behaviors.