Renewable, or green, hydrogen will play a critical role in the decarbonisation of hard-to-abate sectors and will therefore be important in limiting global warming. However, renewable hydrogen is not cost-competitive with fossil fuels, due to the moderate energy efficiency and high capital costs of traditional water electrolysers. Here a unique concept of water electrolysis is introduced, wherein water is supplied to hydrogen- and oxygen-evolving electrodes via capillary-induced transport along a porous inter-electrode separator, leading to inherently bubble-free operation at the electrodes. An alkaline capillary-fed electrolysis cell of this type demonstrates water electrolysis performance exceeding commercial electrolysis cells, with a cell voltage at 0.5 A cm−2 and 85 °C of only 1.51 V, equating to 98% energy efficiency, with an energy consumption of 40.4 kWh/kg hydrogen (vs. ~47.5 kWh/kg in commercial electrolysis cells). High energy efficiency, combined with the promise of a simplified balance-of-plant, brings cost-competitive renewable hydrogen closer to reality.
This work considers the prospects of developing a commercially-feasible water electrolyser with 95–100% energy efficiency (relative to the Higher Heating Value, HHV, of hydrogen) at the cells in the near future.
In this study, new composite materials comprising zeolitic imidazolate framework (ZIF) structures and microchannel glass (MCG) plates were fabricated using the hydrothermal method and their morphological and spectral properties were investigated using XRD, SEM, FTIR, and Raman spectroscopy. XRD studies of powder samples revealed the presence of an additional phase for a ZIF-8 sample, whereas ZIF-67 samples, which were prepared through two different chemical routes, showed no additional phases. A detailed analysis of the FTIR and micro-Raman spectra of the composite samples revealed the formation of stable ZIF structures inside the macropores of the MCG substrate. The hydrophilic nature of the MCG substrate and its interaction with the ZIF structure resulted in the formation of stable ZIF-MCG composites. We believe that these composite materials may find a wide range of important applications in the field of sensors, molecular sieving.
An activated carbon (AC) with a high surface area of 4320.7 m2/g was synthesized via the chemical and thermal processing of walnut residues. The resulting activated charcoal was characterized by various techniques, including Brunauer–Emmett–Teller (BET) surface area analysis, scanning electron microscopy (SEM), and IR spectroscopy. The prepared activated carbon was studied for its capacity to adsorb CO2 gas. When exposed to CO2 for 60 min in a closed chamber at atmospheric pressure at 25 °C, the adsorption of a notable 301.1 mmol CO2 (13.25 g CO2) per gram of activated carbon was observed.
23 June 2023 in Journal of Chemical & Engineering Data