This study systematically reviews the integration of artificial intelligence (AI) and remote sensing technologies to address the issue of crop water stress caused by rising global temperatures and climate change; in particular, it evaluates the effectiveness of various non-destructive remote sensing platforms (RGB, thermal imaging, and hyperspectral imaging) and AI techniques (machine learning, deep learning, ensemble methods, GAN, and XAI) in monitoring and predicting crop water stress. The analysis focuses on variability in precipitation due to climate change and explores how these technologies can be strategically combined under data-limited conditions to enhance agricultural productivity. Furthermore, this study is expected to contribute to improving sustainable agricultural practices and mitigating the negative impacts of climate change on crop yield and quality.
In this study, conventional machine learning and deep leaning approaches were evaluated using X-ray imaging techniques for investigating the internal parameters (endosperm and air space) of three cultivars of watermelon seed. In the conventional machine learning, six types of image features were extracted after applying different types of image preprocessing, such as image intensity and contrast enhancement, and noise reduction. The sequential forward selection (SFS) method and Fisher objective function were used as the search strategy and feature optimization. Three classifiers were tested (linear discriminant analysis (LDA), quadratic discriminant analysis (QDA), and k-nearest neighbors algorithm (KNN)) to find the best performer. On the other hand, in the transfer learning (deep learning) approaches, simple ConvNet, AlexNet, VGG-19, ResNet-50, and ResNet-101 were used to train the dataset and class prediction of the seed. For the supervised model development (both conventional machine learning and deep learning), the germination test results of the samples were used where the seeds were divided into two classes: (1) normal viable seeds and (2) nonviable and abnormal viable seeds. In the conventional classification, 83.6% accuracy was obtained by LDA using 48 features. ResNet-50 performed better than other transfer learning architectures, with an 87.3% accuracy which was the highest accuracy in all classification models. The findings of this study manifested that transfer learning is a constructive strategy for classifying seeds by analyzing their morphology, where X-ray imaging can be adopted as a potential imaging technique.
In this paper, catalyst-free room-temperature healing epoxy vitrimer-like materials (S-vitrimer) are introduced. The S-vitrimer can be healed at room temperature without any external stimuli such as solvent, pressure, heat, and catalyst through an aromatic disulfide exchange reaction and a hydrogen bond because the glass transition temperature of the S-vitrimer is lower than room temperature. Self-healing materials are attracting widespread attention nowadays with their potential to increase the durability of the materials. However, there is still elevating need for research, considering the limitations of various self-healing methods. To the best of our knowledge, epoxy-based catalyst-free room-temperature healing materials have not been investigated until now, yet they are promising to make self-healing easier. Moreover, the S-vitrimer showed higher healing efficiency when healed for a longer time and at a higher temperature. Especially when healed at room temperature for 96 h, the S-vitrimer presented an 80% healing efficiency. The S-vitrimer also showed an 80% healing efficiency when healed at 60 °C for 48 h. To investigate the factors affecting self-healing behavior, three control experiments were carried out. Control experiments showed that the S-vitrimer is healed mainly due to a disulfide exchange reaction, but hydrogen bonds also contribute to self-healing behavior. Also, it was found that tightly packed segments can hinder self-healing through control experiments.
The widely used techniques for analyzing the quality of powdered food products focus on targeted detection with a low-throughput screening of samples. Owing to potentially significant health threats and large-scale adulterations, food regulatory agencies and industries require rapid and non-destructive analytical techniques for the detection of unexpected compounds present in products. Accordingly, shortwave-infrared hyperspectral imaging (SWIR-HSI) for high throughput authenticity analysis of almond powder was investigated in this study. Two different varieties of almond powder, adulterated with apricot and peanut powder at different concentrations, were imaged using the SWIR-HSI system. A one-class classifier technique, known as data-driven soft independent modeling of class analogy (DD-SIMCA), was used on collected data sets of pure and adulterated samples. A partial least square regression (PLSR) model was further developed to predict adulterant concentrations in almond powder. Classification results from DD-SIMCA yielded 100% sensitivity and 89–100% specificity for different validation sets of adulterated samples. The results obtained from the PLSR analysis yielded a high determination coefficient (R2) and low error values (<1%) for each variety of almond powder adulterated with apricot; however, a relatively higher error rates of 2.5% and 4.4% for the two varieties of almond powder adulterated with peanut powder, which indicates the performance of quantitative analysis model could vary with sample condition, such as variety, originality, etc. PLSR-based concentration mapped images visually characterized the adulterant (apricot) concentration in the almond powder. These results demonstrate that the SWIR-HSI technique combined with the one-class classifier DD-SIMCA can be used effectively for a high-throughput quality screening of almond powder regarding potential adulteration.
Aflatoxins and fumonisins, commonly found in maize and maize-derived products, frequently co-occur and can cause dangerous illness in humans and animals if ingested in large amounts. Efforts are being made to develop suitable analytical methods for screening that can rapidly detect mycotoxins in order to prevent illness through early detection. A method for classifying contaminated maize by applying hyperspectral imaging techniques including reflectance in the visible and near-infrared (VNIR) and short-wave infrared (SWIR) regions, and fluorescence was investigated. Machine learning classification models in combination with different preprocessing methods were applied to screen ground maize samples for naturally occurring aflatoxin and fumonisin as single contaminants and as co-contaminants. Partial least squares–discriminant analysis (PLS-DA) and support vector machine (SVM) with the radial basis function (RBF) kernel were employed as classification models using cut-off values of each mycotoxin. The classification performance of the SVM was better than that of PLS-DA, and the highest classification accuracies for fluorescence, VNIR, and SWIR were 89.1%, 71.7%, and 95.7%, respectively. SWIR imaging with the SVM model resulted in higher classification accuracies compared to the fluorescence and VNIR models, suggesting that as an alternative to conventional wet chemical methods, the hyperspectral SWIR imaging detection model may be the more effective and efficient analytical tool for mycotoxin analysis compared to fluorescence or VNIR imaging models. These methods represent a food safety screening tool capable of rapidly detecting mycotoxins in maize or other food ingredients consumed by animals or humans.