The strength–ductility trade-off has long been a Gordian knot in conventional metallic structural materials and it is no exception in multi-principal element alloys. In particular, at ultrahigh yield strengths, plastic instability, that is, necking, happens prematurely, because of which ductility almost entirely disappears. This is due to the growing difficulty in the production and accumulation of dislocations from the very beginning of tensile deformation that renders the conventional dislocation hardening insufficient. Here we propose that premature necking can be harnessed for work hardening in a VCoNi multi-principal element alloy. Lüders banding as an initial tensile response induces the ongoing localized necking at the band front to produce both triaxial stress and strain gradient, which enables the rapid multiplication of dislocations. This leads to forest dislocation hardening, plus extra work hardening due to the interaction of dislocations with the local-chemical-order regions. The dual work hardening combines to restrain and stabilize the premature necking in reverse as well as to facilitate uniform deformation. Consequently, a superior strength-and-ductility synergy is achieved with a ductility of ~20% and yield strength of 2 GPa during room-temperature and cryogenic deformation. These findings offer an instability-control paradigm for synergistic work hardening to conquer the strength–ductility paradox at ultrahigh yield strengths.

Generally, strength and ductility are mutually exclusive in homogeneous metals. Nanostructured metals can have much higher strength when compared to their coarse-grained counterparts, while simple microstructure refinement to nanoscale generally results in poor strain hardening and limited ductility. In recent years, heterogeneous nanostructures in metals have been proven to be a new strategy to achieve unprecedented mechanical properties that are not accessible to their homogeneous counterparts. Here, we review recent advances in overcoming this strength–ductility trade-off by the designs of several heterogeneous nanostructures in metals: heterogeneous grain/lamellar/phase structures, gradient structure, nanotwinned structure and structure with nanoprecipitates. These structural heterogeneities can induce stress/strain partitioning between domains with dramatically different strengths, strain gradients and geometrically necessary dislocations near domain interfaces, and back-stress strengthening/hardening for high strength and large ductility. This review also provides the guideline for optimizing the mechanical properties in heterogeneous nanostructures by highlighting future challenges and opportunities.

The strengthening and ductilization of steels are of great importance to weight reduction of vehicles. In this work, the strength–ductility synergy of dual-phase (DP) steels was obtained by properly tailoring the structural heterogeneity, including the distribution and fraction of constituent phases. It was demonstrated that heterogeneous structural DP steels with high volume fraction of martensite (from 64 to 83%) led to a good combination of strength and ductility. Compared with the cold-rolled sheets, the tensile strength and uniform elongation of heterogeneous DP steel increased by 700 MPa (from 1.06 to 1.76 GPa) and 2.7% (from 1.3 to 4%), respectively. The contributions from back stress and effective stress were analyzed by cyclic loading–unloading experiments. The underlying deformation mechanism was discussed based on the results of mechanical test and microstructure observation.