Photocatalysts with extremely strong reducing potential are often thought to operate through a consecutive photoinduced electron transfer (ConPeT) mechanism, where a first photon generates the radical anion of the photocatalyst via electron transfer and a second photon excites the radical anion into a super-reducing agent. Among them, 4CzIPN, (2,4,5,6-tetrakis(9H-carbazol-9-yl) isophthalonitrile) and the analogous 4DPAIPN (2,4,5,6-tetrakis(diphenylamino)isophthalonitrile) are supposed to operate following this principle, but the knowledge of the photophysical properties of the photogenerated radical anions is still very limited. An in-depth spectroscopic and computational study of their radical anions demonstrates that the excited states of 4CzIPN˙⁻ and 4DPAIPN˙⁻ are not behaving as super-reducing agents: they are very short lived (ca. 20 ps), not emissive and not quenched by common organic substrates. Most importantly, longer lived solvated electrons are generated upon excitation of these radical anions in acetonitrile and we propose that it is the solvated electron the species responsible for the exceptional reducing capability of this photocatalytic system.

Here…comes the fun…Combination of metals and organic photocatalysts allows the practical invention of new methodologies!

Salen ligands are a class of Schiff bases simply obtained through condensation of two molecules of a hydroxyl-substituted aryl aldehyde with an achiral or chiral diamine. The prototype salen, or N,N′-bis(salicylidene)ethylenediamine has a long history, as it was first reported in 1889, and immediately, some of its metal complexes were also described. Now, the salen ligands are a class of N,N,O,O tetradentate Schiff bases capable of coordinating many metal ions. The geometry and the stereogenic group inserted in the diamine backbone or aryl aldehyde backbone have been utilized in the past to efficiently transmit chiral information in a variety of different reactions. In this review we will summarize the important and recent achievements obtained in stereocontrolled reactions in which Al(salen) metal complexes are employed. Several other reviews devoted to the general applications and synthesis of chromium and other metal salens have already been published.

Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(II) complex, [Ru(bpy)₃]²⁺ as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.