Maria J. Sabater

Prof. Maria J. Sabater

Instituto de Tecnología Química, Universitat Politècnica de València, Consejo Superior de Investigaciones Científicas, Av. Los Naranjos s/n, E-46022 Valencia, Spain
orcid

Research Focus & Metrics

Academic Career Length

39Years (1988-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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9 March 2011 in Chemical Reviews
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Journal Article
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ACAvelino Corma
Avelino Corma
ALAntonio Leyva-Pérez
Antonio Leyva-Pérez
Maria J. SabaterMaria J. Sabater
Maria J. Sabater

10 January 2018 in Chemical Reviews
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Journal Article
Open access
ACAvelino Corma
Avelino Corma
JNJavier Navas
Javier Navas
Maria J. SabaterMaria J. Sabater
Maria J. Sabater
The borrowing hydrogen (BH) principle, also called hydrogen auto-transfer, is a powerful approach which combines transfer hydrogenation (avoiding the direct use of molecular hydrogen) with one or more intermediate reactions to synthesize more complex molecules without the need for tedious separation or isolation processes. The strategy which usually relies on three steps, (i) dehydrogenation, (ii) intermediate reaction, and (iii) hydrogenation, is an excellent and well-recognized process from the synthetic, economic, and environmental point of view. In this context, the objective of the present review is to give a global overview on the topic starting from those contributions published prior to the emergence of the BH concept to the most recent and current research under the term of BH catalysis. Two main subareas of the topic (homogeneous and heterogeneous catalysis) have been identified, from which three subheadings based on the source of the electrophile (alkanes, alcohols, and amines) have been considered. Then the type of bond being formed (carbon–carbon and carbon heteroatom) has been taken into account to end-up with the intermediate reaction working in tandem with the metal-catalyzed hydrogenation/dehydrogenation step. The review has been completed with the more recent advances in asymmetric catalysis using the BH strategy.

1 September 2004 in Nature
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Journal Article
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ACAvelino Corma
Avelino Corma
FRFernando Rey
Fernando Rey
JRJordi Rius
Jordi Rius
Maria J. SabaterMaria J. Sabater
Maria J. Sabater
Susana ValenciaSusana Valencia
Susana Valencia

4 August 2013 in Nature Chemistry
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Journal Article
Closed access
ACAvelino Corma
Avelino Corma
Patricia ConcepcionPatricia Concepcion
Patricia Concepcion
MBMercedes Boronat
Mercedes Boronat
Maria J. SabaterMaria J. Sabater
Maria J. Sabater
JNJavier Navas
Javier Navas
Alvaro MayoralAlvaro Mayoral
Alvaro Mayoral

23 January 2014 in ACS Catalysis
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Journal Article
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MCMaria J. Climent
Maria J. Climent
ACAvelino Corma
Avelino Corma
SISara Iborra
Sara Iborra
Maria J. SabaterMaria J. Sabater
Maria J. Sabater

1 January 1997 in Chemical Communications
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Journal Article
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Maria J. SabaterMaria J. Sabater
Maria J. Sabater
ACAvelino Corma
Avelino Corma
ADAntonio Domenech
Antonio Domenech
VFVicente Fornés
Vicente Fornés
HGHermenegildo García
Hermenegildo García
A chiral (salen)Mn III complex [salen: trans-(R,R)-1,2-bis(salicylideneamino)cyclohexane] analogous to Jacobsen’s catalyst is prepared inside the supercages of zeolite Y, showing catalytic activity very similar to that of the chloride complex in the homogeneous phase.