In this paper, a flexible Ag/CNTs-PDMS (polydimethylsi-loxane) composite film sensor based on the novel design philosophy was prepared. Its force-electric effect mechanism is based on the generation of micro-cracks in the Ag film during external forcing, leading to resistance variation. Experimental results find that Ag film thickness has a strong influence on the sensor’s sensitivity, which exhibits a tendency of first increasing and then decreasing the Ag film thickness, and also has an optimal thickness of 4.9 μm for the maximum sensitivity around 30. The sensitive mechanism can be theoretically explained by using the quantum tunneling effect. Due to the use of the wrinkled carbon nanotubes (CNTs) film, this sensor has advantages, such as high sensitivity, large strain range, good stability and durability, cheap price, and suitability for large-scale production. Preliminary applications on human-body monitoring reveal that the sensor can detect weak tremors and breathe depth and rate, and the corresponding heartbeat response. It provides possibilities to diagnose early Parkinson’s disease and exploit an early warning system for sudden infant death syndrome and sleep apnea in adults. In addition, as a force-electric effect sensor, it is expected to have broad application areas, such as a man-machine cooperation, and a robotic system.
In general, during long-term museum conservation, ancient bronzes will generate new corrosion products also called the “secondary corrosion” on the surface of the unearthed “primary corrosion” products due to various environmental conditions. In this paper, the corrosion stages of several ancient Chinese bronzes are characterized by using optical microscope (OM), scanning electron microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD) and Raman spectrometer (Raman). It is found that there exist phase transformation relationships in between the “primary corrosion” and the “secondary corrosion” stages (i.e., (1) the crystal lattice type tends to transform from a high symmetry system to a low symmetry system; (2) in case of the same crystal lattice type, the corrosions exhibit an inter-transformation or symbiosis). It is interesting to note that these transformation rules are very consistent with the well-known physical law of “spontaneous symmetry-breaking”, which won the 2008 Nobel Prize in Physics and also has been considered to be general law of nature, in addition to the principle of Gibbs free energy reduction. The significance of this discovery allows us to achieve the predictability and controllability of the bronze corrosion products (i.e., to predict the corrosive trends in advance and control the “second corrosion” by adjusting the conservation conditions. This research provides a novel conservation concept of ancient bronzes.