The effect of substituting CaO with BaO and CaO/Al₂O₃ ratio on the viscosity of CaO–BaO–Al₂O₃–CaF₂–Li₂O mold flux system was studied by rotational viscosity method. The results showed that the viscosity increased with increasing BaO as a substitute for CaO, while the viscosity decreased with the increase in CaO/Al₂O₃ ratio. The viscous activation energy of the slags is from 92.1 kJ·mol⁻¹ to 133.4 kJ·mol⁻¹. Either the Arhenius or the Weymann–Frenkel equation can be applied to establish the viscosity prediction model. In this paper, the Weymann–Frenkel equation and a new optical basicity with regard to Al₂O₃ as an acidic oxide were applied to the modified NPL model for predicting the viscosity of CaO–BaO–Al₂O₃–CaF₂–Li₂O mold flux system. The estimated viscosity is in good agreement with the measured viscosity.

During the continuous casting (CC) of Ti-bearing steel, a steel lump can solidify in the mold (i.e., floater steel) more easily than in the Ti-free steels. This causes severe surface defects or even a breakout. We have examined the mechanisms of floater formation during the CC of 321 stainless steel by analyzing the inclusions in the floater steel and in the 321 steel that was sampled from the mold. Additionally, we calculated the disregistry between the metallic phases and common inclusions. The mineralogy and morphology of the inclusions were examined while using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Thermodynamic calculations on the Ti_xO_y inclusions at different oxygen potentials were performed while using FactSage 7.2. Using this approach, we determined that ferrite nucleates grow on TiN and MgO inclusions following solidification, which then form micro-aggregates as a result of dynamic collisions and alliances. Analysis of the mold slag from the metallurgy stage indicated that altering the basicity and properties of the mold flux systematically might minimize the reaction between the slag and steel, which would achieve a coordinated control over lubrication and heat transfer.

The effect of nonsinusoidal oscillation at different modification ratios (α) on slag lubrication was investigated during mold oscillation. A validated and reliable multiphase model was employed, which involved flow and solidification of the molten steel and mold slag. The main results revealed that a large amount of liquid slag at the entrance of the mold–strand channel reflowed into the slag pool at the middle of the negative strip period. The phenomenon was more distinct, with an increase in the modification ratio. The modification ratio had no obvious effect on the average thickness of the liquid film at different depths below the meniscus. A modification ratio of 0.5 caused less fluctuation of the transient liquid film. Quantitative prediction of slag consumption indicated that as the modification ratio increased from 0.2 to 0.5 to 0.8, the average values were 0.278, 0.286, and 0.279 kg/m², respectively. Shell solidification and growth near the meniscus mainly occurred when the mold was descending, which not only depended on the heat flux, but also on the liquid slag flow, the pressure driven by slag rim, and the mold oscillation. Optimization of the modification ratio of nonsinusoidal oscillation could be an alternative to delay growth of the initial shell towards the molten steel. A modification ratio of 0.5 had the least robust shell tip at the meniscus, thereby reducing entrapment of inclusions and bubbles by the shell tip.