With the ever increasing demand for energy to meet the needs of growth in population and improvement in the living standards, in particular in developing countries, the abundant unconventional oil reserves (about 70% of total world oil), such as heavy oil, oil/tar sands and shale oil, are playing an increasingly important role in securing global energy supply.

Oil–water emulsions are widely generated in industries, which may facilitate some processes (e.g., transportation of heavy oil, storage of milk, synthesis of chemicals or materials, etc.) or lead to serious upgrading or environmental issues (e.g., pipeline plugging, corrosions to equipment, water pollution, soil pollution, etc.). Herein, the sources, classification, formation, stabilization, and separation of oil–water emulsions are systematically summarized. The roles of different interfacially active materials–especially the fine particles–in stabilizing the emulsions have been discussed. The advanced development of micro force measurement technologies for oil–water emulsion investigation has also been presented. To provide insights for future industrial application, the separation of oil–water emulsions by different methods are summarized, as well as the introduction of some industrial equipment and advanced combined processes. The gaps between some demulsification processes and industrial applications are also touched upon. Finally, the development perspectives of oil–water treatment technology are discussed for the purpose of achieving high-efficiency, energy-saving, and multi-functional treatment. We hope this review could bring forward the challenges and opportunities for future research in the fields of petroleum production, coal production, iron making, and environmental protection, etc.

Novel core–shell structured ellipsoid-like BiVO₄@g-C₃N₄ composites, with different amounts of g-C₃N₄, have been successfully prepared by a simple hydrothermal-chemisorption method.

A new, simple one-step approach has been developed to synthesize lignin and lignin amine coated Fe₃O₄ nanoparticles. These nanoparticles (lignin magnetic nanoparticles (LMNPs) and lignin amine magnetic nanoparticles (LAMNPs)) are found to possess not only magnetic response but also pH-dependent adsorption behavior. Results show that the combination of lignin with nanoparticles increased the adsorption capacities 2–5 times higher than other traditional single lignin based adsorbents (211.42 mg/g for methylene blue (MB) by LMNPs and 176.49 mg/g for acid scarlet GR (AS-GR) by LAMNPs). Meanwhile, by simply adjusting the pH, the dye-loaded adsorbents can be regenerated to recycle both adsorbents and dyes with a desorption efficiency up to 90%. Mechanistic study shows that dye structure and surface charges of adsorbents play the most important part in adsorption where dyes interact with the adsorbent surface via π–π stacking and electrostatic attraction interactions. The efficient fabrication method, eco-friendly reactant, quick magnetic separation, high adsorption and desorption efficiency suggest this novel type of nano-adsorbents to be promising materials for efficient dye pollutant removal and recovery.