Styrene Butadiene Styrene (SBS) polymer-modified asphalt binders have become widely used in asphalt pavement because of their advantages in high- and low-temperature performance and fatigue resistance. Asphalt pavement is inevitably exposed to sunlight and ultraviolet (UV) radiation during its construction and service life. However, consideration of the aging effect of UV radiation is still limited in current pavement design and evaluation systems. In order to evaluate the impact of UV radiation on the aging properties of SBS-modified asphalt binders, UV aging tests were performed on Rolling Thin Film Oven Test (RTFOT)-aged samples with different UV radiation intensities and aging times. Sixteen different groups of tests were conducted to compare the rheological properties and functional group characteristics of SBS-modified asphalt binders. Dynamic Shear Rheometer (DSR), Bending Beam Rheometer (BBR), FTIR, and SEM tests were conducted to evaluate the aging mechanisms in various UV aging conditions. The results found that UV radiation seriously destroys the network structure formed by the cross-linking effect in SBS-modified asphalt binders, which aggravates the degradation of SBS and results in a great change of rheological properties after UV aging. The nature of SBS-modified asphalt binder aging resulted from the degradation of SBS and the changes of asphalt binder base composition, which lead to the transformation of colloidal structure and the deterioration of asphalt binder performance. The tests also found that continuous UV radiation can increase shrinkage stress in the asphalt binder surface and leads to surface cracking of the asphalt binder.

Aggregate occupies at least three-quarters of the volume of asphalt mixture and can significantly affect the performance of pavement. The geometrical morphology influences the slippage and interlock among aggregates for resisting and distributing applied loads. In recent years, the discrete-element method (DEM) has been employed for simulation of asphalt mixture structure. This paper introduces an approach for simulation of aggregate and asphalt mixtures using parameterized shape and size gradation. Both the plane geometry factor (PGF) and the section aspect ratio (SAR) were employed to describe the three-dimensional (3D) geometric characteristics of aggregates. A numerical technique of aggregate models was implemented with probabilistic parameters depending on statistical results of PGFs and SARs. The 3D numerical model of asphalt mixtures was assembled with three different components, and was validated by uniaxial compression tests via comparison with the laboratory result. It was found that the PGF and SAR are appropriate to describe the three-dimensional features of aggregate shapes, because a simplified space object can be described by a two-dimensional (2D) graphical projection and a vector scalar corresponding to the space vector. Probability distribution curves of PGFs and SARs between coarse aggregates were in concordance with the Gauss-type function, because their correlation coefficients were all greater than 95%. It was verified that the developed clumping algorithm of aggregates was reasonable in terms of the shape and size gradation. Based on the parallel-bond model and Burger’s model, the results of virtual tests were in good agreement with those of laboratory uniaxial tests. The angularity (PGF) of aggregates has a beneficial effect on the strength and stability of asphalt mixtures, whereas the flat-elongated feature (SAR) has a negative effect on the strength and stability of asphalt mixtures.

The NO_x degradation performance of nano-TiO₂ as a coating material for the road environment was evaluated in this research. The nano-TiO₂ coating materials for both road surface and roadside were prepared by using anatase nano-TiO₂, activated carbon powder, silane coupling agent and deionized water. The impact of varying amounts of coating material and silane coupling agent were evaluated. The road environment of NO_x degradation was simulated by the photocatalytic test system designed by the research team. For the road surface coating, the photocatalytic degradation experiments of NO under different radiation intensities were carried out. The results show that the material has good photocatalytic degradation performance, and the proper amount of silane coupling agent can enhance the bonding performance of the material and asphalt mixture. For the roadside coating, sodium dodecylbenzene sulfonate was selected as the surfactant to carry out the photocatalytic degradation experiment of NO₂ with different dosages of surfactant. The results showed that when the mass ratio of nano-TiO₂ and surfactant was about 1:2, the catalytic degradation effect of the material was the best.

Bitumen aging can lead to the deterioration of asphalt pavement performance, shortening the service life of road. In order to solve the problem that current studies on the ultraviolet (UV) aging of bitumen either ignore the effects of natural environmental conditions or only consider the effects of water. In this study, different aqueous media and UV coupled simulated aging tests were carried out on virgin bitumen and styrene butadiene styrene (SBS) modified bitumen in a UV environment chamber. The combination of macroscopic performance tests and microstructure tests was used to analyze the physical, rheological, and microstructure changes of virgin bitumen and SBS modified bitumen after The film oven test (TFOT) aging and UV aging in different environments (UV, UV + Water, UV + Acid, UV + Salt). Dynamic shear rheometer (DSR) results indicated that UV aging results in the increase of rutting factor and the improvement of rutting resistance at high temperature. The Fourier transform infrared spectrum (FTIR) results illustrated that the bitumen would be oxidized and SBS would be degraded under ultraviolet radiation. The four-component analysis test results showed that light component migrated to the heavy component during the aging process. Moreover, water will aggravate the UV aging of bitumen, and the presence of acid or salt worsens ultraviolet aging.