Bimetallic Pt–Ni catalysts can promote catalytic dry reforming of methane (DRM) with improved activity and deactivation resistance compared to the relevant monometallic catalysts. Further development of Pt–Ni catalysts requires mechanistic insights into the catalytic system. Herein, a mechanistic study of DRM over Pt–Ni supported on cerium oxide catalysts (i.e., Pt–Ni@CeO₂) was performed using in situ coupled diffuse reflectance infrared Fourier-transform spectroscopy and mass spectrometry (DRIFTS-MS). Specifically, a comparative study of DRM over Pt–Ni@CeO₂ and control materials under continuous temperature ramping, isothermal steady-state and fast cycling transient conditions was conducted to gain information on the key surface active intermediates. As compared with the Ni@CeO₂ monometallic catalyst, the bimetallic Pt–Ni@CeO₂ catalyst showed significantly enhanced performance regarding activity, H₂/CO ratio and long-term stability. In situ DRIFTS measurements revealed that CH₄ decomposition on the surface of monometallic Ni phases readily caused serious coke deposition and deactivation. Conversely, the Pt phase in the bimetallic catalyst could improve CO₂ dissociation, thus producing adsorbed oxygen species, which are beneficial for oxidising surface carbon species (derived from CH₄ decomposition) to reduce coke formation. Meanwhile, the existence of Pt sites in the bimetallic catalyst could significantly improve metal dispersion, and thus facilitate the decomposition of CH₄.

A newly developed DRIFTS cell for the in situ study of non-thermal plasma-assisted heterogeneously catalysed reactions is presented and evaluated using methane oxidation over a Pd/Al₂O₃ catalyst.

Enhanced interaction between metal precursors and silanol nests was demonstrated on a silanol-rich dealuminated beta zeolite by strong electrostatic adsorption, leading to the formation of highly dispersed Ni nanoparticles for effective catalysis.