The Lower Cambrian black shales of the Sansui vanadium deposits, located in South China, host a thin accumulation of Ni, Mo, V, and platinum group of elements (PGE). However, among them, the origin of V-bearing deposits remains controversial. To characterize the enrichment process of V-bearing deposits, samples of the mineralized layer and surrounding rocks from the Sansui area, South China, were investigated through bulk geochemical analysis and scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) analyses. There is a consistency in the change curves of Mo, Ni, and V from the Sansui V deposits, but the contents of elements show a great difference. This means the strong similarities in the metal sources but a difference in enrichment factors of Mo, Ni, and V. The presence of the tuff and the barite layer in the Sansui V deposits indicates that the formation of the associated V deposits was closely related to either a volcanic or hydrothermal activity. Analysis of geochemistry and sedimentation suggests a hydrothermal source of the metals, where the mineralization of V is related to clay and organic matter. Phosphorus nodules were observed at all sites of black shale V deposits in early Cambrian and were most likely related to the upwelling currents during the depositional period. The comparison with the Ni–Mo deposits highlights a stronger enrichment of clay in the V deposits. The V deposits are located in the lower part of the continental slope. Both organic matter and clay minerals are abundant in the Sansui deposits. However, the isomorphism of V–Al is promoted by the hydrothermal activity and suggests that the origin of V deposits is a multistage process.

The Nibao gold deposit, which includes both fault-controlled and strata-bound gold orebodies, constitutes an important part of the Yunnan–Guizhou–Guangxi “Golden Triangle” region. Defining the mineralization age of these gold orebodies may provide additional evidence for constraining the formation ages of low-temperature orebodies and their metallogenic distribution in South China. Petrographic studies of gold-bearing pyrites and ore-related quartz veins indicate that these pyrites coexist with quartz or filled in vein-like quartz, which suggests a possible genetic relationship between the two from Nibao gold deposit. Minerals chemistry shows that Rb and Sr are usually hosted in fluid inclusions in quartz ranging from 0.0786 to 2.0760 ppm and 0.1703 to 2.1820 ppm, respectively. The Rb–Sr isotopic composition of gold-bearing quartz-hosted fluid inclusions from the Nibao gold deposit were found to have Rb–Sr isochron ages of 142 ± 3 and 141 ± 2 Ma for both fault-controlled and strata-bound orebodies, respectively, adding more evidence to previous studies and thus revealing a regional gold mineralization age of 148–134 Ma. These results also confirm the Middle-Late Yanshanian mineralizing events of Carlin-type gold deposits in Yunnan, Guizhou, and Guangxi Provinces of Southwest China. In addition, previous studies indicated that antimony deposits in the region which were formed at ca. 148–126 Ma have a close affinity with gold deposits. This illustrates that the regional low-temperature hydrothermal gold mineralization is related in space and time to the Yanshanian (ca. 146–115 Ma) magmatic activity. Specifically, the large-scale gold and antimony mineralization are considered to be inherently related to mantle-derived mafic and ultramafic magmatic rocks associated with an extensional tectonic environment. Based on the initial ⁸⁷Sr/⁸⁶Sr ratios of 0.70844 ± 0.00022 (2σ) and 0.70862 ± 0.00020 (2σ) for gold-bearing quartz veins from fault-controlled and strata-bound gold orebodies, respectively, at the Nibao gold deposit, as well as the C, H, O, and S isotopic characteristics of gold deposits located in the Golden Triangle region, we suggest that the mantle-derived material can be involved in the formation of the Nibao gold deposit and that the ore-forming fluid can be derived from a mixed crust–mantle source.

Karst bauxite is a major source of aluminum and contains high concentrations of trace elements such as Li, Ga, Sc, and rare earth elements (REEs). It is regarded as a potential non-conventional REE source due to the increasing demand for REEs. This study provides new mineralogical and geochemical evidence of a Lindai bauxite deposit in central Guizhou Province, aiming to analyze the genesis of REE minerals and reveal the forms of REEs occurring in these deposits. The results indicate that a large number of detrital and authigenic rare-earth phosphate minerals, including monazite and xenotime, were identified. In terms of their genesis, the authigenic monazite was mainly precipitated under alkaline and reducing conditions, whereas the authigenic xenotime was formed in acidic and reducing conditions. The mineralogical evidence detected by scanning electron microscopy with energy dispersive spectrometry (SEM-EDS) and a TESCAN Integrated Mineral Analyzer (TIMA) suggests that the REEs in the Lindai bauxite exhibit multiple forms, including rare-earth phosphate minerals (monazite and xenotime) and REE scavenging by hematite and anatase phases. Among them, the anatase controls some LREE (such as La, Ce, and Pr) distributions in addition to monazite, whereas the hematite also controls relatively large amounts of Sm, Eu, and HREE (such as Gd, Tb, Dy, Ho, Er, Tm, and Lu) distributions. According to the calculation of the percentage of REE-bearing mineral phases obtained by a TIMA analysis, REE scavenging by hematite accounted for 93.28% of all forms of REEs, REE scavenging by anatase accounted for 5.88%, monazite accounted for 0.67%, and xenotime accounted for 0.17%. This study provides new evidence of the forms of REEs occurring in Carboniferous karst bauxite in central Guizhou Province.