To better understand the source and health risk of metal elements in PM_2.5, a field study was conducted from May to December 2018 in the central region of the Liaoning province, China, including the cities of Shenyang, Anshan, Fushun, Benxi, Yingkou, Liaoyang, and Tieling. 24 metal elements (Na, K, V, Cr, Mn, Co, Ni, Cu, Zn, As, Mo, Cd, Sn, Sb, Pb, Bi, Al, Sr, Mg, Ti, Ca, Fe, Ba, and Si) in PM_2.5 were measured by ICP-MS and ICP-OES. They presented obvious seasonal variations, with the highest levels in winter and lowest in summer for all seven cities. The sum of 24 elements were ranged from to in these cities. The element mass concentration ratio was the highest in Yingkou in the spring (26.15%), and the lowest in Tieling in winter (3.63%). The highest values of elements in PM_2.5 were mostly found in Anshan and Fushun among the studied cities. Positive matrix factorization (PMF) modelling revealed that coal combustion, industry, traffic emission, soil dust, biomass burning, and road dust were the main sources of measured elements in all cities except for Yingkou. In Yingkou, the primary sources were identified as coal combustion, metal smelting, traffic emission, soil dust, and sea salt. Health risk assessment suggested that Mn had non-carcinogenic risks for both adults and children. As for Cr, As, and Cd, there was carcinogenic risks for adults and children in most cities. This study provides a clearer understanding of the regional pollution status of industrial urban agglomeration.

The mechanism of the chemical reaction of H₂O with three stabilized Criegee intermediates (stabCI-OO, stabCI-CH₃-OO and stabCIx-OO) produced via the limonene ozonolysis reaction has been investigated using ab initio and DFT (Density Functional Theory) methods. It has been shown that the formation of the hydrogen-bonded complexes is followed by two different reaction pathways, leading to the formation of either OH radicals via water-catalyzed H migration or of α-hydroxy hydroperoxide. Both pathways were found to be essential sources of atmospheric OH radical and H₂O₂ making a significant contribution to the formation of secondary aerosols in the Earth’s atmosphere. The activation energies at the CCSD(T)/6-31G(d) + CF level of theory were found to be in the range of 14.70–21.98 kcal mol⁻¹. The formation of α-hydroxy hydroperoxide for the reaction of stabCIx-OO and H₂O with the activation energy of 14.70 kcal mol⁻¹ is identified as the most favorable pathway.

Urban and suburban PM_2.5 samples were collected simultaneously during selected periods representing each season in 2019 in Zibo, China. Samples were analysed for water-soluble inorganic ions, carbon components, and elements. A chemical mass balance model and health risk assessment model were used to investigate the source contributions to PM_2.5 and the human health risks posed by various pollution sources via the inhalation pathway. Almost 50% of the PM_2.5 samples exceeded the secondary standard of China’s air quality concentration limit (75 µg/m³, 24 h). Water-soluble inorganic ions were the main component of PM_2.5 in Zibo, accounting for 50 ± 8% and 56 ± 11% of PM_2.5 at the urban and suburban sites, respectively. OC and OC/EC decreased significantly in the past few years due to enhanced energy restructuring. Pearson correlation analysis showed that traffic emissions were the main source of heavy metals. The Cr(VI) concentrations were 1.53 and 1.92 ng/m³ for urban and suburban sites, respectively, exceeding the national ambient air quality standards limit of 0.025 ng/m³. Secondary inorganic aerosols, traffic emissions, and secondary organic aerosols were the dominant contributors to PM_2.5 in Zibo, with the total contributions from these three sources accounting for approximately 80% of PM_2.5 and the remaining 20% attributed to traffic emissions. The non-carcinogenic risks from crustal dust for children were 2.23 and 1.15 in urban and suburban areas, respectively, exceeding the safe limit of 1.0 in both locations, as was the case for adults in urban areas. Meanwhile, the carcinogenic risks were all below the safe limit, with the non-carcinogenic and carcinogenic risks from traffic emissions being just below the limits. Strict control of precursor emissions, such as SO₂, NOx, and VOCs, is a good way to reduce PM_2.5 pollution resulting from secondary aerosols. Traffic control, limiting or preventing outdoor activities, and wearing masks during haze episodes may be also helpful in reducing PM_2.5 pollution and its non-carcinogenic and carcinogenic health impacts in Zibo.

As one of the biggest cities in North China, Jinan has been suffering heavy air pollution in recent decades. To better characterize the ambient particulate matter in Jinan during heavy pollution periods, we collected daily PM_2.5 (particulate matter with aerodynamic diameters equal to or less than 2.5 μm) filter samples from 15 October 2017 to 31 January 2018 and analyzed their chemical compositions (including inorganic water-soluble ions (WSIs), carbonaceous species, and inorganic elements). The daily average concentration of PM_2.5 was 83.5 μg/m³ during the sampling period. A meteorological analysis revealed that both low wind speed and high relative humidity facilitated the occurrence of high PM_2.5 pollution episodes. A chemical analysis indicated that high concentrations of water-soluble ions, carbonaceous species, and elements were observed during heavy pollution days. The major constituents of PM_2.5 in Jinan were secondary aerosol particles and organic matter based on the results of mass closure. Chemical Mass Balance (CMB) was used to track possible sources and identified that nitrate, sulfate, vehicle exhaust and coal fly ash were the main contributors to PM_2.5 during heavy pollution days in Jinan, accounting for 25.4%, 18.6%, 18.2%, and 13.3%, respectively.