Due to the declining of oil reserves in the world in the coming decades, gas hydrate (GH) is seen as the great promise to supply the planet’s energy demand. With this, the importance of studying the behavior of GH, several researchers have been developing different systems that allow greater truthfulness in relation to the conditions where GH is found in nature. This work describes a new system to simulate formation (precipitation) and dissociation of GH primarily at natural conditions at deep-sea, lakes, and permafrost, but also applied for artificial gas hydrates studies (pipelines, and transport of hydrocarbons, CO₂, and hydrogen). This system is fully automated and unique, allowing the simultaneous work in two independent reactors, built in Hastelloy C-22, with a capacity of 1 L and 10 L, facilitating rapid analyses when compared to higher-volume systems. The system can operate using different mixtures of gases (methane, ethane, propane, carbon dioxide, nitrogen, ammonia), high pressure (up to 200 bar) with high operating safety, temperature (−30 to 200 °C), pH controllers, stirring system, water and gas samplers, and hyphenated system with gas chromatograph (GC) to analyze the composition of the gases formed in the GH and was projected to possibility the visualizations of experiments (quartz windows).

Tuberculosis remains a global health problem that affects millions of people around the world. Despite recent efforts in drug development, new alternatives are required. Herein, a series of 27 N-(4-(benzyloxy)benzyl)-4-aminoquinolines were synthesized and evaluated for their ability to inhibit the M. tuberculosis H37Rv strain. Two of these compounds exhibited minimal inhibitory concentrations (MICs) similar to the first-line drug isoniazid. In addition, these hit compounds were selective for the bacillus with no significant change in viability of Vero and HepG2 cells. Finally, chemical stability, permeability and metabolic stability were also evaluated. The obtained data show that the molecular hits can be optimized aiming at the development of drug candidates for tuberculosis treatment.

Polypropylene (PP) is one of the most widely used polymers in the world, mainly due to its versatility, good properties, and low cost. However, since it is not easily degraded in the natural environment, several research projects have been developed to increase its biodegradability. The use of pro-degrading additives has been explored, as they promote the process of polymer degradation. Nevertheless, few studies have evaluated the degradation of these materials in natural aqueous environments such as rivers and lakes, which contain large amounts of PP waste. The goal of this study was to evaluate the degradation of polypropylene, as well as the biodegradation of PP through the incorporation of two additives of different natures, organic and enzymatic. For this purpose, PP blends were produced with 4% additive, which has the purpose of conferring biodegradability to the material, since polypropylene has high resistance to degradation. In order to verify the behavior of the materials against degradation tests with 2 different media (saline and fresh water) for a period of 6 months, the samples were characterized by Fourier Transformed Infrared Spectroscopy and Field emission scanning electron microscopy. The characterizations were carried out in order to verify the changes in the structural characteristics and in the morphology of the materials caused by the incorporation of the additive and by the exposure to the degradation media. From the results obtained, it was observed that the additives influenced the degradation of PP. In addition, the enzyme additive and the saline media caused more significant changes in the properties analyzed, indicating greater influence on the degradation process. It was concluded that the incorporation of commercial additives gives biodegradable properties to PP. Therefore, this study has an important role in the research and development of biodegradable materials in order to minimize the effects caused by plastic waste in the environment. Thus, the studied materials are an alternative in the field of plastic packaging, reducing the effects caused by plastic waste in the environment.

The carbon dioxide sorption process at coal seams is very important for understanding the trapping mechanisms of carbon capture and storage. The gas retention capacity of coal seams can be estimated using indirect methods based on the adsorption/desorption isotherms obtained in the laboratory. However, the gas sorption capacity can be overestimated or underestimated depending on the sample preparation. This work evaluates different sample preparations and their theoretical adsorption capacity using coal samples from the Cambui coal field (Parana Basin), southern Brazil. Experiments using a thermogravimetric balance were done to calculate the theoretical adsorption capacity, while sample characterization was done through immediate analysis, elementary analysis, and mineralogical studies. The sample preparations used in this work were powder, pellets, and fragments. While the powder form presents an average behavior, without any experimental complication, the pellet is extremely sensitive to any variation in the sample preparation, such as fractures, and the fragment requires a much longer experiment time than the other sample preparations, being impracticable for some cases.

Purification of biodiesel with dry adsorbents is an alternative method, as it uses compounds that eliminate the need for water in the process without generating liquid effluent. Currently, there is little discussion about the reuse of different types of adsorbents and in this context, the present work presents an efficient method of purification and investigates the performance of the reuse of Magnesol® in the purification of biodiesel in order to generate less waste to the environment. Therefore, the Magnesol® used was washed with several solvents with different polarity characteristics. Among the solvents tested, THF is the best solvent for the purification of Magnesol® and, after optimizing the Magnesol® purification process, it was concluded the best conditions are three washes in solvent / adsorbent ratio 30:1 at room temperature, resulting in only 3.89% of the residual value of contaminants and being an alternative for biodiesel companies.

O presente artigo busca, por meio da análise do comportamento humano quanto à interpretação de informações e dos sistemas de compartilhamento e recomendação dos principais meios de comunicação, definir os fatores que levaram o fenômeno das fake news a tornar-se um problema de escala global e presente no cotidiano de um grande número de usuários de internet e outras redes sociais. Para tanto, procuramos estudar os processos cerebrais envolvidos na absorção e na separação de uma informação que levam as notícias falsas a serem tão disseminadas. Além disso, analisou-se a verificação do sistema de recomendação seletiva e sem moderação dos conteúdos repassados para cada usuário. Este trabalho relaciona tais aspectos para entender, de forma geral, como o aumento do uso das redes sociais redundou em tal fenômeno.