The chemical routes of metal oxidation in presence of hydrogen peroxide solutions are tailor-made for the synthesis of biocompatible metal oxide surfaces with clean intermediate and end products, such as oxides, hydroxides, hydrogen and water. The hydrolysis of titanium in hydrogen peroxide solutions is particularly interesting for medical applications, forming micro- and nanoscale titania surfaces. In this paper, the content of the hydrolysis solution is revised, allowing the fabrication of gas sensor devices based on nanoporous titania. Nanopore and microcrack formations were discussed in detail by monitoring the structural changes on the thin film surface with field-emission scanning electron microscopy (FE-SEM). A stable rutile crystalline phase was detected by glancing incidence X-ray diffraction (GI-XRD) measurement after repetitive hydrothermal processes. Electrical conductance measurements were carried out at high temperatures (400–600 °C) under humid airflow (40% RH@20 °C) with the injection of various concentrations of a wide set of test compounds (C₂H₃N, CO, H₂, NO₂, C₂H₆O), to observe the sensing capabilities of the material. Furthermore, the humidity effects on the sensing properties toward H₂, CO, and C₂H₆O have been discussed.

The surface of SnO₂ nanowires was functionalized by chitosan for the development of room-temperature conductometric humidity sensors. SnO₂ nanowires were synthesized by the seed-mediated physical-vapor-deposition (PVD) method. Chitosan layers were deposited on top of the SnO₂ nanowires by spin coating. Surface morphology, crystal structure, and optical properties of the synthesized hybrid nanostructure were investigated by scanning electron microscope, grazing incidence X-ray diffraction, and UV–Vis absorption measurements. During electrical conductivity measurements, the hybrid nanostructure showed unusual behavior towards various relative humidity (RH) concentrations (25%, 50%, 75%), under UV-light irradiation, and in dark conditions. The highest sensor responses were recorded towards an RH level of 75%, resulting in 1.1 in the dark and 2.5 in a UV-irradiated chamber. A novel conduction mechanism of hybrid nanowires is discussed in detail by comparing the sensing performances of chitosan film, SnO₂ nanowires, and chitosan@SnO₂ hybrid nanostructures.

In recent years, metal-organic frameworks (MOFs) have emerged as promising materials for biomedical applications, owing to their superior chemical versatility, unique textural properties and enhanced mechanical properties. However, their fast and uncontrolled degradation, together with the reduced bioactivity have restricted their clinical potential. To overcome these limitations, MOFs can be synergistically combined with other materials, such as bioactive glasses (BGs), known for their bioactivity and therapeutic ion releasing capabilities. Besides comparing MOFs and BGs, this review aims to present the latest achievements of different MOFs/BGs materials, with a particular focus on their complementary and synergistic properties. Key findings show that combining MOFs and BGs enables the development of composite materials with superior physicochemical and biological properties. Moreover, by choosing appropriate processing techniques, BGs and MOFs can be fabricated as scaffolds or coatings with fast mineralization ability and high corrosion resistance. In addition, incorporation of MOFs/BGs in hydrogels improves mechanical stability, bioactivity and antibacterial properties, while maintaining biocompatibility. The mechanisms behind the antibacterial properties, likely coming from the release of metal ions and organic ligands, are also discussed. Overall, this review highlights the current research directions and emerging trends in the synergistic use of MOFs and BGs for biomedical applications, which represents a novel strategy for developing a new family of advanced therapeutic materials.

The effects of the porosity and the thickness on the ability of hydrogen sensing is demonstrated through a comparison of compact and nanoporous platinum film sensors. The synthesis of anodic aluminum oxide (AAO) nanotubes with an average pore diameter of less than 100 nm served as the template for the fabrication of nanoporous Pt films using an anodization method. This was achieved by applying a voltage of 40 V in 0.4 M of a phosphoric acid solution at 20 °C. To compare the film and nanoporous Pt, layers of approximately 3 nm and 20 nm were coated on both glass substrates and AAO templates using a sputtering technique. FESEM images monitored the formation of nanoporosity by observing the Pt layers covering the upper edges of the AAO nanotubes. Despite their low thickness and the poor long-range order, the EDX and XRD measurements confirmed and uncovered the crystalline properties of the Pt films by comparing the bare and the Pt deposited AAO templates. The nanoporous Pt and Pt thin film sensors were tested in the hydrogen concentration range between 10–50,000 ppm H₂ at room temperature, 50 °C, 100 °C and 150 °C. The results reveal that nanoporous Pt performed higher sensitivity than the Pt thin film and the surface scattering phenomenon can express the hydrogen sensing mechanism of the Pt sensors.